Structure and Reactivity of Gas‐Phase Molybdenum Oxide Cluster Ions Full article
Journal |
Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
||
---|---|---|---|
Output data | Year: 2002, Volume: 43, Number: 5, Pages: 777-782 Pages count : 6 DOI: 10.1023/A:1022821223313 | ||
Tags | Oxide; Oxygen; Inorganic Chemistry; Carbon Monoxide; Molybdenum | ||
Authors |
|
||
Affiliations |
|
Funding (2)
1 | International Science Foundation | RBG 000 |
2 | International Science Foundation | RBG 300 |
Abstract:
Combining the ion cyclotron resonance method and a Knudsen effusion source, we obtained a series of MoxOy + (x = 1 – 5, y = 1 – 15) molybdenum oxide cluster ions. We studied the dependence of the concentrations of these ions on the trapping time and their reactions with carbon monoxide. It is shown that MoxOy + ions with x > 3 contain a cyclic Mo3O9 fragment in their structure. The oxygen bond energies in MoxOy + ionic clusters are estimated.
Cite:
Goncharov V.B.
, Fialko E.F.
Structure and Reactivity of Gas‐Phase Molybdenum Oxide Cluster Ions
Journal of Structural Chemistry. 2002. V.43. N5. P.777-782. DOI: 10.1023/A:1022821223313 WOS Scopus РИНЦ
Structure and Reactivity of Gas‐Phase Molybdenum Oxide Cluster Ions
Journal of Structural Chemistry. 2002. V.43. N5. P.777-782. DOI: 10.1023/A:1022821223313 WOS Scopus РИНЦ
Original:
Гончаров В.Б.
, Фиалко Е.Ф.
Исследование структуры и реакционной способности ионных кластеров оксида молибдена в газовой фазе
Журнал структурной химии. 2002. Т.43. №5. С.838-843. РИНЦ
Исследование структуры и реакционной способности ионных кластеров оксида молибдена в газовой фазе
Журнал структурной химии. 2002. Т.43. №5. С.838-843. РИНЦ
Dates:
Submitted: | Aug 13, 2001 |
Published print: | Sep 1, 2002 |
Identifiers:
Web of science | WOS:000181881800011 |
Scopus | 2-s2.0-0036956546 |
Elibrary | 13394415 |
Chemical Abstracts | 2003:213362 |
Chemical Abstracts (print) | 139:12955 |
OpenAlex | W121440640 |