X-Ray Spectral and Photoelectron Study of the Electronic Structure of Copper Phthalocyanine and Its Fluoro-Substituted Analog Full article
Journal |
Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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Output data | Year: 2012, Volume: 53, Number: 6, Pages: 1046-1055 Pages count : 10 DOI: 10.1134/S0022476612060054 | ||||||||
Tags | charge transfer model, photoelectron spectroscopy, phthalocyanines, X-ray emission spectroscopy | ||||||||
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Abstract:
A complex experimental study of Cu(2p 3/2), Cu(2p 1/2) photoelectron and Kα1,2 and Lα1,2 X-ray emission spectra of copper in copper phthalocyanine CuPcH16 and its fluoro-substituted analog CuPcF16 is carried out. A charge transfer model is used to interpret the spectra. It is shown that Kα1 and Kα2 lines of the spindoublet of copper have a complex structure due to the processes of metal-to-ligand charge transfer. The role of a satellite in the formation of emission lines is revealed.
Cite:
Mazalov L.N.
, Semushkina G.I.
, Lavrukhina S.A.
, Korotaev E.V.
, Boronin A.I.
, Gulyaev R.V.
, Basova T.V.
X-Ray Spectral and Photoelectron Study of the Electronic Structure of Copper Phthalocyanine and Its Fluoro-Substituted Analog
Journal of Structural Chemistry. 2012. V.53. N6. P.1046-1055. DOI: 10.1134/S0022476612060054 WOS Scopus РИНЦ
X-Ray Spectral and Photoelectron Study of the Electronic Structure of Copper Phthalocyanine and Its Fluoro-Substituted Analog
Journal of Structural Chemistry. 2012. V.53. N6. P.1046-1055. DOI: 10.1134/S0022476612060054 WOS Scopus РИНЦ
ArticleLinkType.TRANSLATED_TO_ORIGINAL:
Мазалов Л.Н.
, Семушкина Г.И.
, Лаврухина С.А.
, Коротаев Е.В.
, Боронин А.И.
, Гуляев Р.В.
, Басова Т.В.
Рентгеноспектральное и рентгеноэлектронное изучение электронного строения фталоцианина меди и его фторзамещенного аналога
Журнал структурной химии. 2012. Т.53. №6. С.1074-1083. RSCI РИНЦ
Рентгеноспектральное и рентгеноэлектронное изучение электронного строения фталоцианина меди и его фторзамещенного аналога
Журнал структурной химии. 2012. Т.53. №6. С.1074-1083. RSCI РИНЦ
Dates:
Submitted: | May 31, 2012 |
Published print: | Nov 1, 2012 |
Published online: | Feb 2, 2013 |
Identifiers:
Web of science | WOS:000314365600005 |
Scopus | 2-s2.0-84873351039 |
Elibrary | 20483218 |
Chemical Abstracts | 2013:189500 |
Chemical Abstracts (print) | 159:50725 |
OpenAlex | W1997871076 |