Hydroxides of Transition Metals as Artificial Catalysts for Oxidation of Water to Dioxygen Review
Conference |
Photochemical Conversion and Storage of Solar Energy: 12th International conference 09-14 Aug 1998 , Berlin |
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Journal |
Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308 |
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Output data | Year: 2000, Volume: 58, Number: 2-3, Pages: 71-88 Pages count : 8 DOI: 10.1016/S0920-5861(00)00243-1 | ||
Tags | Transition metals; Artificial catalysts; Dioxygen evolution; Photosystem II; Aqueous solutions; Hydroxides | ||
Authors |
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Affiliations |
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Funding (2)
1 | Russian Foundation for Basic Research | 98-03-32410 |
2 | Council for Grants of the President of the Russian Federation | 96-10-15-97586 |
Abstract:
Hydroxides of transition metals cations like Fe(III), Co(III), Mn(III), Ru(IV), etc., appear to be efficient artificial catalysts in oxidation of water to O2. The paper describes some catalytic properties of these hydroxides. The hydroxide-based catalysts for the water oxidation can be obtained in three modifications: bulky (individual and binary), supported on the ion exchange resins or conventional oxide supports (SiO2, TiO2, Al2O3, zeolites), and colloidal catalysts stabilized by starch. The possible mechanism of the catalytic reaction, including the stage of the formation of peroxocomplexes as intermediates is under discussion. Some similarities are drawn between the catalytic properties of hydroxide catalysts and those of the manganese-based oxygen evolving complex of the Photosystem II of green plants.
Cite:
Elizarova G.L.
, Zhidomirov G.M.
, Parmon V.N.
Hydroxides of Transition Metals as Artificial Catalysts for Oxidation of Water to Dioxygen
Catalysis Today. 2000. V.58. N2-3. P.71-88. DOI: 10.1016/S0920-5861(00)00243-1 WOS Scopus РИНЦ
Hydroxides of Transition Metals as Artificial Catalysts for Oxidation of Water to Dioxygen
Catalysis Today. 2000. V.58. N2-3. P.71-88. DOI: 10.1016/S0920-5861(00)00243-1 WOS Scopus РИНЦ
Dates:
Published online: | Apr 18, 2000 |
Published print: | May 12, 2000 |
Identifiers:
Web of science | WOS:000087198800003 |
Scopus | 2-s2.0-0033752126 |
Elibrary | 13352114 |
Chemical Abstracts | 2000:258957 |
Chemical Abstracts (print) | 132:339799 |
OpenAlex | W2026951811 |