X-Ray Photoelectron Investigation of Charge Distribution in Copper(II) Phthalocyanine Complexes Full article
Journal |
Journal of Surface Investigation: X-Ray, Synchrotron and Neutron Techniques
ISSN: 1027-4510 , E-ISSN: 1819-7094 |
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Output data | Year: 2011, Volume: 5, Number: 1, Pages: 48-56 Pages count : 9 DOI: 10.1134/S1027451011010101 | ||||
Tags | Phthalocyanine; Surface Investigation; Macrocycle; Neutron Technique; Copper Phthalocyanine | ||||
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Abstract:
The charged states of atoms in unsubstituted copper(II) phthalocyanine (CuPcH16) and hexade-cafluorinated copper(II) phthalocyanine (CuPcF16) complexes and in thin films of them deposited on silicon substrates by vacuum thermal evaporation are investigated by X-ray photoelectron spectroscopy (XPS). The C(1s), N(1s), Cu(2p) core level energies and the charged states of atoms in the studied complexes are calculated using the DFT method. The performed experimental study and theoretical calculations show that the introduction of electron acceptor substituents into benzene rings mostly affects the atoms of benzene rings and insignificantly affects the charge state of nitrogen atoms in the pyrrole ring.
Cite:
Gulyaev R.V.
, Kryuchkova N.A.
, Mazalov L.N.
, Boronin A.I.
, Basova T.V.
, Plyashkevich V.A.
X-Ray Photoelectron Investigation of Charge Distribution in Copper(II) Phthalocyanine Complexes
Journal of Surface Investigation: X-Ray, Synchrotron and Neutron Techniques. 2011. V.5. N1. P.48-56. DOI: 10.1134/S1027451011010101 WOS Scopus РИНЦ
X-Ray Photoelectron Investigation of Charge Distribution in Copper(II) Phthalocyanine Complexes
Journal of Surface Investigation: X-Ray, Synchrotron and Neutron Techniques. 2011. V.5. N1. P.48-56. DOI: 10.1134/S1027451011010101 WOS Scopus РИНЦ
Original:
Гуляев Р.В.
, Крючкова Н.А.
, Мазалов Л.Н.
, Боронин А.И.
, Басова Т.В.
, Пляшкевич В.А.
Рентгеноэлектронное изучение зарядового распределения в комплексах фталоцианинов меди( II)
Поверхность. Рентгеновские, синхротронные и нейтронные исследования. 2011. №1. С.53-61. РИНЦ
Рентгеноэлектронное изучение зарядового распределения в комплексах фталоцианинов меди( II)
Поверхность. Рентгеновские, синхротронные и нейтронные исследования. 2011. №1. С.53-61. РИНЦ
Dates:
Submitted: | Jul 23, 2010 |
Published print: | Feb 1, 2011 |
Published online: | Feb 20, 2011 |
Identifiers:
Web of science | WOS:000289904500009 |
Scopus | 2-s2.0-79951985624 |
Elibrary | 16873265 |
Chemical Abstracts | 2011:215511 |
Chemical Abstracts (print) | 155:255525 |
OpenAlex | W2016189443 |