Novel Heterometallic Palladium-Silver Complex Full article
Journal |
Inorganica Chimica Acta
ISSN: 0020-1693 , E-ISSN: 1873-3255 |
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Output data | Year: 2011, Volume: 370, Number: 1, Pages: 382-387 Pages count : 6 DOI: 10.1016/j.ica.2011.02.003 | ||||||||
Tags | Heterometallic complexes, Palladium, Quantum-chemical analysis, Silver, Thermal decomposition, X-ray structure | ||||||||
Authors |
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Affiliations |
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Funding (6)
1 | Russian Foundation for Basic Research | 09-03-00514 |
2 | Russian Foundation for Basic Research | 09-03-12114 |
3 | Council for Grants of the President of the Russian Federation | НШ-65264.2010.3 |
4 | Russian Foundation for Basic Research | 10-03-90420 |
5 | Russian Foundation for Basic Research | 11-03-01157 |
6 | Президиум РАН |
Abstract:
The reaction between Pd3(OOCMe)6 and Ag2(OOCMe)2 afforded the first palladium–silver heterometallic acetate-bridged complex PdII[(μ-OOCMe)2AgI(HOOCMe)2]2 (1). The molecular geometry and electronic structure of 1 were studied by single-crystal XRD and quantum-chemical DFT calculations. Thermal transformations of 1in vacuo and under Ar, H2 produced PdAg alloy nanoparticles characterized with powder XRD and EXAFS
Cite:
Kozitsyna N.Y.
, Nefedov S.E.
, Klyagina A.P.
, Markov A.A.
, Dobrokhotova Z.V.
, Velikodny Y.A.
, Kochubey D.I.
, Zyubina T.S.
, Gekhman A.E.
, Vargaftik M.N.
, Moiseev I.I.
Novel Heterometallic Palladium-Silver Complex
Inorganica Chimica Acta. 2011. V.370. N1. P.382-387. DOI: 10.1016/j.ica.2011.02.003 WOS Scopus РИНЦ
Novel Heterometallic Palladium-Silver Complex
Inorganica Chimica Acta. 2011. V.370. N1. P.382-387. DOI: 10.1016/j.ica.2011.02.003 WOS Scopus РИНЦ
Dates:
Submitted: | Dec 22, 2010 |
Accepted: | Feb 1, 2011 |
Published online: | Mar 5, 2011 |
Published print: | May 1, 2011 |
Identifiers:
Web of science | WOS:000289556300055 |
Scopus | 2-s2.0-79954620281 |
Elibrary | 20532149 |
Chemical Abstracts | 2011:476279 |
Chemical Abstracts (print) | 154:630161 |
OpenAlex | W2024575155 |