Solid-Phase Condensation of Rhodium(III) Aqua Sulfates Full article
Journal |
Russian Journal of Inorganic Chemistry
ISSN: 0036-0236 , E-ISSN: 1531-8613 |
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Output data | Year: 2011, Volume: 56, Number: 10, Pages: 1609-1616 Pages count : 8 DOI: 10.1134/S0036023611100263 | ||||
Tags | Rhodium; Weight Loss Curve; Aqua Sulfate; Cesium Nitrate; Sulfate Bridge | ||||
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Abstract:
Solid-phase condensation of rhodium(III) aqua sulfates yielding oligomeric rhodium(III) aqua sulfate complexes was revealed. The isothermal dehydration of rhodium(III) aqua sulfates under thermal diffusion conditions in the temperature range 100–130°C was studied, and effective rate constants and activation energies were determined. The solid phases of dehydration products were studied by X-ray powder diffraction and IR spectroscopy, and solutions of polymeric phases were studied by 103Rh and 17O NMR, electronic absorption spectroscopy, chromatography, and electrophoresis.
Cite:
Vorobʹyova S.N.
, Belyaev A.V.
, Fedotov M.A.
, Yushina I.V.
, Nedoseikina T.I.
Solid-Phase Condensation of Rhodium(III) Aqua Sulfates
Russian Journal of Inorganic Chemistry. 2011. V.56. N10. P.1609-1616. DOI: 10.1134/S0036023611100263 WOS Scopus РИНЦ
Solid-Phase Condensation of Rhodium(III) Aqua Sulfates
Russian Journal of Inorganic Chemistry. 2011. V.56. N10. P.1609-1616. DOI: 10.1134/S0036023611100263 WOS Scopus РИНЦ
ArticleLinkType.TRANSLATED_TO_ORIGINAL:
Воробьёва С.Н.
, Беляев А.В.
, Федотов М.А.
, Юшина И.В.
, Недосейкина Т.И.
Твердофазная конденсация сульфатов акваиона родия(III)
Журнал неорганической химии. 2011. Т.56. №10. С.1689-1696. РИНЦ
Твердофазная конденсация сульфатов акваиона родия(III)
Журнал неорганической химии. 2011. Т.56. №10. С.1689-1696. РИНЦ
Dates:
Submitted: | May 12, 2010 |
Published print: | Oct 1, 2011 |
Published online: | Oct 11, 2011 |
Identifiers:
Web of science | WOS:000295784600017 |
Scopus | 2-s2.0-80053977387 |
Elibrary | 18009132 |
Chemical Abstracts | 2011:1287093 |
Chemical Abstracts (print) | 157:307187 |
OpenAlex | W2078238873 |