Transformations of 1-(2-Aminophenyl)propan-2-ol to 2-Methylindoline Full article
Journal |
Catalysis Letters
ISSN: 1011-372X , E-ISSN: 1572-879X |
||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|
Output data | Year: 2015, Volume: 145, Pages: 955-963 Pages count : 9 DOI: 10.1007/s10562-014-1474-3 | ||||||||||
Tags | Acidity, Alcohols, Amines, Zeolites | ||||||||||
Authors |
|
||||||||||
Affiliations |
|
Funding (2)
1 | European Commission | 246095 FP7-NMP-2009-LARGE-3 POLYCAT |
2 | Åbo Akademi University |
Abstract:
The transformation reaction of 1-(2-aminophenyl)propan-2-ol was studied at 200 C under argon pressure. A range of catalysts was applied including carbon, titania and zeolite supported Ru, Pd, Pt, Rh, and Ir, as well as metal free zeolites. The highest conversion was obtained with H-Beta-150 and H-Beta-25 and the highest selectivity to
2-methylindoline was achieved with 0.3 % Ir–H-Beta-150 and H-Beta-25. Although the selectivity to 2-methylindole was high for all catalysts, formation of the final product 2-methylindoline only took place over the most acidic catalysts.
Cite:
Bernas H.
, Demidova Y.S.
, Aho A.
, Simakova I.L.
, Kumar N.
, Laribi Y.
, Perrichon P.
, Leino R.
, Murzin D.Y.
Transformations of 1-(2-Aminophenyl)propan-2-ol to 2-Methylindoline
Catalysis Letters. 2015. V.145. P.955-963. DOI: 10.1007/s10562-014-1474-3 WOS Scopus РИНЦ
Transformations of 1-(2-Aminophenyl)propan-2-ol to 2-Methylindoline
Catalysis Letters. 2015. V.145. P.955-963. DOI: 10.1007/s10562-014-1474-3 WOS Scopus РИНЦ
Dates:
Submitted: | Nov 21, 2014 |
Accepted: | Dec 29, 2014 |
Published online: | Jan 10, 2015 |
Published print: | Mar 1, 2015 |
Identifiers:
Web of science | WOS:000350677000026 |
Scopus | 2-s2.0-84938394654 |
Elibrary | 23995566 |
Chemical Abstracts | 2015:67471 |
Chemical Abstracts (print) | 162:326791 |
OpenAlex | W2080908063 |