Unique Shortening of Carbon Chain During Reduction of Aliphatic Nitro Compounds to Amines in the Presence of Supercritical Isopropanol on Alumina Full article
Journal |
The Journal of Supercritical Fluids
ISSN: 0896-8446 , E-ISSN: 1872-8162 |
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Output data | Year: 2015, Volume: 103, Pages: 101-104 Pages count : 4 DOI: 10.1016/j.supflu.2015.04.029 | ||||||
Tags | Aliphatic amine, Alumina, Hydrogen transfer, Nitro group, Reduction, Supercritical isopropanol | ||||||
Authors |
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Affiliations |
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Funding (1)
1 | Russian Foundation for Basic Research | 14-08-00210 |
Abstract:
Transformations of lower aliphatic nitrocompounds in supercritical isopropanol in a flow reactor in the presence of alumina were studied. In experiments with 1-nitropropane, the dominant process was the never-before-observed formation of an amine with a shorter by one carbon atom chain as compared to the initial nitroalkane. The reaction mechanism was suggested which adequately explained the formation of all detected products. The reactions of nitroethane and nitromethane partly proceeded by a new transformation route yielding isopropylamine
Cite:
Sivcev V.P.
, Volcho K.P.
, Salakhutdinov N.F.
, Anikeev V.I.
Unique Shortening of Carbon Chain During Reduction of Aliphatic Nitro Compounds to Amines in the Presence of Supercritical Isopropanol on Alumina
The Journal of Supercritical Fluids. 2015. V.103. P.101-104. DOI: 10.1016/j.supflu.2015.04.029 WOS Scopus РИНЦ
Unique Shortening of Carbon Chain During Reduction of Aliphatic Nitro Compounds to Amines in the Presence of Supercritical Isopropanol on Alumina
The Journal of Supercritical Fluids. 2015. V.103. P.101-104. DOI: 10.1016/j.supflu.2015.04.029 WOS Scopus РИНЦ
Dates:
Submitted: | Jan 21, 2015 |
Accepted: | Apr 28, 2015 |
Published online: | May 7, 2015 |
Published print: | Aug 1, 2015 |
Identifiers:
Web of science | WOS:000356984100013 |
Scopus | 2-s2.0-84929629404 |
Elibrary | 47506584 |
Chemical Abstracts | 2015:835442 |
Chemical Abstracts (print) | 163:161111 |
OpenAlex | W589617809 |