Observing the Orbital Ordering of Ti(III) Ions in Catalysts for the Polymerization of Diene Compounds Full article
Journal |
Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X |
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Output data | Year: 2016, Volume: 90, Number: 2, Pages: 282-285 Pages count : 4 DOI: 10.1134/S0036024416020072 | ||||
Tags | EPR, orbital ordering, trivalent titanium | ||||
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Abstract:
The orbital ordering of Ti(III) ions is observed via EPR spectroscopy for the catalytic system TiCl4 + TIBA in an isopentane solution with an excess of organoaluminum compound. A model of the alternating ground states of 3d 1 ions (d xy and dz2 is proposed for the ordered structures. Ti(III) ions with the d xy ground states are mono- and dialkylated
Cite:
Biktagirov V.V.
, Anufrienko V.F.
, Biktagirova E.V.
Observing the Orbital Ordering of Ti(III) Ions in Catalysts for the Polymerization of Diene Compounds
Russian Journal of Physical Chemistry A. 2016. V.90. N2. P.282-285. DOI: 10.1134/S0036024416020072 WOS Scopus РИНЦ
Observing the Orbital Ordering of Ti(III) Ions in Catalysts for the Polymerization of Diene Compounds
Russian Journal of Physical Chemistry A. 2016. V.90. N2. P.282-285. DOI: 10.1134/S0036024416020072 WOS Scopus РИНЦ
Original:
Биктагиров В.В.
, Ануфриенко В.Ф.
, Биктагирова Е.В.
Обнаружение орбитального упорядочения ионов ti(iii) в катализаторах полимеризации диеновых соединений
Журнал физической химии. 2016. Т.90. №2. С.178-181. DOI: 10.7868/S0044453716020072 РИНЦ
Обнаружение орбитального упорядочения ионов ti(iii) в катализаторах полимеризации диеновых соединений
Журнал физической химии. 2016. Т.90. №2. С.178-181. DOI: 10.7868/S0044453716020072 РИНЦ
Dates:
Submitted: | Feb 16, 2015 |
Published online: | Jan 7, 2016 |
Published print: | Feb 1, 2016 |
Identifiers:
Web of science | WOS:000368190500006 |
Scopus | 2-s2.0-84953432084 |
Elibrary | 26929599 |
Chemical Abstracts | 2016:40458 |
OpenAlex | W2286393980 |