N2O Reduction by CO over Pt Electrode in a Solid Oxide Electrolyte Cell Full article
Journal |
Catalysis Letters
ISSN: 1011-372X , E-ISSN: 1572-879X |
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Output data | Year: 1999, Volume: 57, Number: 1-2, Pages: 43-47 Pages count : 5 DOI: 10.1023/A:1019014725066 | ||
Tags | Carbon monoxide, Nitrous oxide, Platinum, Reduction, Solid oxide electrolyte cell | ||
Authors |
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Affiliations |
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Funding (1)
1 | International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union | 94-3056 |
Abstract:
The reduction of nitrous oxide by carbon monoxide in a cell with a solid oxygen-conducting electrolyte - CO + N2O, Pt | 0.9ZrO2 + 0.1Y2O3 | Pt + PrO2, air - was studied. Experiments were performed in the temperature range 410-670°C. The reaction kinetics under open-circuit conditions and the effect of current passing through the cell on the reaction rate were found to depend on the gaseous composition. In particular: (i) for a reaction mixture rich in N2O, in contrast to the reaction mixture rich in CO, the temperature steady-state multiplicity of the reaction was observed under open-circuit conditions; (ii) for the reaction mixture rich in CO, in contrast to the reaction mixture rich in N2O, a slight non-Faradaic enhancement of the reaction rate upon cathodic current application was demonstrated.
Cite:
Belyaev V.D.
, Politova T.I.
, Sobyanin V.A.
N2O Reduction by CO over Pt Electrode in a Solid Oxide Electrolyte Cell
Catalysis Letters. 1999. V.57. N1-2. P.43-47. DOI: 10.1023/A:1019014725066 WOS Scopus РИНЦ
N2O Reduction by CO over Pt Electrode in a Solid Oxide Electrolyte Cell
Catalysis Letters. 1999. V.57. N1-2. P.43-47. DOI: 10.1023/A:1019014725066 WOS Scopus РИНЦ
Dates:
Submitted: | Jul 14, 1998 |
Accepted: | Dec 3, 1998 |
Published print: | Feb 1, 1999 |
Identifiers:
Web of science | WOS:000078792000007 |
Scopus | 2-s2.0-0004537371 |
Elibrary | 13325580 |
Chemical Abstracts | 1999:172233 |
Chemical Abstracts (print) | 130:215035 |
OpenAlex | W97404396 |