Cobalt Phthalocyanine Derivatives Supported on TiO2 by Sol-Gel Processing. Part 1: Preparation and Microstructure Full article
Journal |
Chemische Berichte (now European Journal of Inorganic Chemistry)
ISSN: 0009-2940 |
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Output data | Year: 1997, Volume: 130, Number: 11, Pages: 1585-1589 Pages count : 5 DOI: 10.1002/cber.19971301106 | ||||||
Tags | Heterogenous catalysis, Phthalocyanines, Sol-gel processes, Supported catalysts, Titanium alkoxides | ||||||
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Abstract:
Cobalt(II) 2,9,16,23-tetrasulphophthalocyanine and cobalt(II) 2,9,16,23-tetra(chlorosulphonyl)phthalocyanine were supported on TiO2 by reaction of the phthalocyanines with Ti(OR)4 followed by sol-gel synthesis. The thus obtained solid materials are stable in sulfide-containing media and are therefore suitable as catalysts for HS oxidation. The structure of the samples was characterized by electron microscopy diffraction. The morphology of the matrix strongly depends on the cobalt phthalocyanine derivative. The pathalocyanines in the titania matrices are monomeric or dimeric depending both on the type of substituents of the CoPc derivative and on the titanium alkoxide used as precursors.
Cite:
Schubert U.
, Lornez A.
, Kundo N.
, Stuchinskaya T.
, Gogina L.
, Salanov A.
, Zaikovskii V.
, Maizlish V.
, Shaposhnikov G.P.
Cobalt Phthalocyanine Derivatives Supported on TiO2 by Sol-Gel Processing. Part 1: Preparation and Microstructure
Chemische Berichte (now European Journal of Inorganic Chemistry). 1997. V.130. N11. P.1585-1589. DOI: 10.1002/cber.19971301106 WOS Scopus РИНЦ
Cobalt Phthalocyanine Derivatives Supported on TiO2 by Sol-Gel Processing. Part 1: Preparation and Microstructure
Chemische Berichte (now European Journal of Inorganic Chemistry). 1997. V.130. N11. P.1585-1589. DOI: 10.1002/cber.19971301106 WOS Scopus РИНЦ
Dates:
Submitted: | Jun 19, 1997 |
Published print: | Nov 1, 1997 |
Published online: | Jan 30, 2006 |
Identifiers:
Web of science | WOS:A1997YE65100004 |
Scopus | 2-s2.0-0002874439 |
Elibrary | 13267110 |
Chemical Abstracts | 1997:718458 |
Chemical Abstracts (print) | 128:7654 |
OpenAlex | W2125189902 |