Formation of Carboxylic Acids from Small Alkanes in Xeolite H-ZSM-5 Full article
Journal |
Chemistry - A European Journal
ISSN: 0947-6539 , E-ISSN: 1521-3765 |
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Output data | Year: 2000, Volume: 6, Number: 13, Pages: 2368-2376 Pages count : 9 DOI: 10.1002/1521-3765(20000703)6:13<2368::AID-CHEM2368>3.0.CO;2-H | ||||
Tags | Alkanes, Carbon monoxide, Carboxylic acids, NMR spectroscopy, Zeolites | ||||
Authors |
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Affiliations |
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Funding (2)
1 | International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union | 95-IN-RU-194 |
2 | University of Southern California |
Abstract:
The activation of propane and isobutane in acidic zeolite H-ZSM-5 in the presence of both CO and H2O has been studied by in situ solid-state NMR and GC analysis. Evidence was provided for the conversion of propane to isobutyric acid at 373–473 K by cleavage of the C[BOND]C bond; methane and ethane are also produced. Isobutane is transformed into pivalic acid with simultaneous production of hydrogen. The low conversion (1–2 %) at this temperature was rationalized by the existence of a small number of sites that are capable of generating carbenium ions which are trapped by CO at this temperature. A formate species was observed when CO and H2O were present on H-ZSM-5. This species disappeared in the presence of the alkane. At 573 K, the generation of large amounts of CO2 indicates a much higher conversion of the alkanes into carboxylic acids which, however, decompose under the reaction conditions.
Cite:
Luzgin M.V.
, Stepanov A.G.
, Sassi A.
, Sommer J.
Formation of Carboxylic Acids from Small Alkanes in Xeolite H-ZSM-5
Chemistry - A European Journal. 2000. V.6. N13. P.2368-2376. DOI: 10.1002/1521-3765(20000703)6:13<2368::AID-CHEM2368>3.0.CO;2-H WOS Scopus РИНЦ
Formation of Carboxylic Acids from Small Alkanes in Xeolite H-ZSM-5
Chemistry - A European Journal. 2000. V.6. N13. P.2368-2376. DOI: 10.1002/1521-3765(20000703)6:13<2368::AID-CHEM2368>3.0.CO;2-H WOS Scopus РИНЦ
Dates:
Submitted: | Sep 10, 1999 |
Published online: | Jun 26, 2000 |
Published print: | Jul 3, 2000 |
Identifiers:
Web of science | WOS:000088278300009 |
Scopus | 2-s2.0-0034601023 |
Elibrary | 13344252 |
Chemical Abstracts | 2000:514811 |
Chemical Abstracts (print) | 133:252032 |
OpenAlex | W2084537427 |