Selective Low-Temperature Transformation of Methane into C2-C4 Alkenes in the Presence of a Hydrogen-Accumulating System Full article
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Doklady Physical Chemistry
ISSN: 0012-5016 , E-ISSN: 1608-3121 |
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Output data | Year: 1998, Volume: 361, Number: 4-6, Pages: 276-279 Pages count : 4 | ||
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Abstract:
Low-temperature conversion of CH4 in alkenes in the presence of H-accumulating system able to activate C-H bonds with subsequent removal of H from the reaction mixture was studied. The catalyst was a mixture of cylinders of highly purified Ti containing 0.4% wt. Ni and chips of highly purified Ti. The catalyst was activated by thermal treatment. Mechanism of formation of olefins is discussed. Conversion of methane at low temperature was 20% wt.; olefin content was 68-73% from it. 50-55% Wt. of all olefins was ethylene.
Cite:
Tsodikov M.V.
, Slivinskii E.V.
, Mordovin V.P.
, Shestakov A.F.
, Kochubey D.I.
, Ivanov V.P.
, Bukhtenko O.V.
, Navío J.
Selective Low-Temperature Transformation of Methane into C2-C4 Alkenes in the Presence of a Hydrogen-Accumulating System
Doklady Physical Chemistry. 1998. V.361. N4-6. P.276-279. Scopus РИНЦ
Selective Low-Temperature Transformation of Methane into C2-C4 Alkenes in the Presence of a Hydrogen-Accumulating System
Doklady Physical Chemistry. 1998. V.361. N4-6. P.276-279. Scopus РИНЦ
Original:
Цодиков М.В.
, Сливинский Е.В.
, Мордовин В.П.
, Шестаков А.Ф.
, Кочубей Д.И.
, Иванов В.П.
, Бухтенко О.В.
, Навио Х.А.
Селективное низкотемпературное превращение метана в алкены C2-C4 в присутствии водородаккумулирующей системы
Доклады Академии наук. 1998. Т.361. №6. С.791-794. РИНЦ
Селективное низкотемпературное превращение метана в алкены C2-C4 в присутствии водородаккумулирующей системы
Доклады Академии наук. 1998. Т.361. №6. С.791-794. РИНЦ
Dates:
Submitted: | Feb 11, 1998 |
Published print: | Aug 1, 1998 |
Identifiers:
Scopus | 2-s2.0-27144496180 |
Elibrary | 13281071 |
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