CsLiB6O10 Crystals with Cs Deficit: Structure and Properties Full article
Journal |
Journal of Crystal Growth
ISSN: 0022-0248 |
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Output data | Year: 2005, Volume: 282, Number: 3-4, Pages: 407-413 Pages count : 7 DOI: 10.1016/j.jcrysgro.2005.05.032 | ||||||
Tags | A1. Defect structure, A1. Hydration, B2. Optical materials | ||||||
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Abstract:
Cs–Li borate crystals (CLBO) grown from melts have been examined by chemical and thermal analysis and IR spectroscopy. Evaporation of cesium oxides from melt during growing resulted in crystals with Cs deficit. The defect structure of these crystals has been refined by means of single-crystal X-ray diffraction analysis, while two non equivalent Cs positions have been revealed. Using the close-packed spheres model, the volumes of the structural vacant spaces have been estimated, and the proof of their occupation by one or several water molecules has been given. The behavior of the defect CLBO crystals exposed to dry and moist atmospheres has been considered.
Cite:
Isaenko L.
, Vasilyeva I.
, Merkulov A.
, Tomilenko A.
, Bogdanova I.
, Malakhov V.
, Drebushhak V.
CsLiB6O10 Crystals with Cs Deficit: Structure and Properties
Journal of Crystal Growth. 2005. V.282. N3-4. P.407-413. DOI: 10.1016/j.jcrysgro.2005.05.032 WOS Scopus РИНЦ
CsLiB6O10 Crystals with Cs Deficit: Structure and Properties
Journal of Crystal Growth. 2005. V.282. N3-4. P.407-413. DOI: 10.1016/j.jcrysgro.2005.05.032 WOS Scopus РИНЦ
Dates:
Submitted: | Mar 18, 2005 |
Accepted: | May 10, 2005 |
Published online: | Jun 21, 2005 |
Published print: | Sep 1, 2005 |
Identifiers:
Web of science | WOS:000231429500020 |
Scopus | 2-s2.0-23144433000 |
Elibrary | 13490644 |
Chemical Abstracts | 2005:698060 |
Chemical Abstracts (print) | 143:336596 |
OpenAlex | W2003374984 |