Similarities between Reactions of Methanol with MoxOy+ in the Gas Phase and over Real Catalysts Full article
Journal |
The Journal of Physical Chemistry B
ISSN: 1520-6106 , E-ISSN: 1520-5207 |
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Output data | Year: 1997, Volume: 101, Number: 30, Pages: 5772-5773 Pages count : 2 DOI: 10.1021/JP963848B | ||
Tags | Aromatic hydrocarbons; Atoms; Catalysts; Cyclotron resonance; Ions; Methanol; Molecules; Molybdenum compounds; Olefins; Paraffins; Protons; Reaction kinetics | ||
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Abstract:
ICR studies of the interactions between methanol and the family of MoxOy+ ions (x = 1−3, y = 1−9) in the gas phase are reported. Molybdenum oxide ions participate in four types of reactions with the CH3OH molecule that show rather profound similarities with the reactions of methanol over heterogeneous and homogeneous catalysts containing molybdenum−oxygen sites. Molybdenum oxide ions with three metal atoms represent coupling of two and three hydrocarbon fragments of CH3OH to form longer hydrocarbon chains. The formation of acidic proton of MoxOyH+ (x = 1−3, y = 2−9) was found in interactions with CH3OH2+ and its solvates CH3OH2+·(CH3OH)n with n = 1, 2. Acidic protons are able to provide coupling of hydrocarbon fragments of alcohol molecules to produce finally alkenes and alkanes.
Cite:
Fialko E.F.
, Kikhtenko A.V.
, Goncharov V.B.
, Zamaraev K.I.
Similarities between Reactions of Methanol with MoxOy+ in the Gas Phase and over Real Catalysts
The Journal of Physical Chemistry B. 1997. V.101. N30. P.5772-5773. DOI: 10.1021/JP963848B WOS Scopus РИНЦ
Similarities between Reactions of Methanol with MoxOy+ in the Gas Phase and over Real Catalysts
The Journal of Physical Chemistry B. 1997. V.101. N30. P.5772-5773. DOI: 10.1021/JP963848B WOS Scopus РИНЦ
Dates:
Submitted: | Nov 18, 1996 |
Accepted: | May 27, 1997 |
Published print: | Jul 1, 1997 |
Published online: | Jul 24, 1997 |
Identifiers:
Web of science | WOS:A1997XM73100002 |
Scopus | 2-s2.0-0031189104 |
Elibrary | 43189750 |
Chemical Abstracts | 1997:425396 |
Chemical Abstracts (print) | 127:135485 |
OpenAlex | W1996670135 |