On the Dependence of Surface Tension of Liquids on the Curvature of the Liquid-Vapor Interface Full article
Journal |
The Journal of Physical Chemistry B
ISSN: 1520-6106 , E-ISSN: 1520-5207 |
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Output data | Year: 2001, Volume: 105, Number: 5, Pages: 1050-1055 Pages count : 6 DOI: 10.1021/jp9929972 | ||||||
Tags | NUCLEATION THEORY; ADSORPTION DATA; MESOPORE SIZE; FREE-ENERGY; PORE-SIZE | ||||||
Authors |
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Affiliations |
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Funding (2)
1 | Russian Foundation for Basic Research | 98-03-32390 |
2 | International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union | IR-97-0676 |
Abstract:
Conventional methods for measuring pore-size distribution (PSD), which are based on the capillary condensation (CC) and mercury intrusion porosimetry (MIP), are very sensitive to the numerical values of surface tension, σ, of the corresponding liquid phase. However, it is generally accepted that σ strongly depends on the curvature radius, r. Hence, PSD measuring seems unreliable if it does not involve the σ(r) dependence. Experimental studies of the surface tension, σ, for nuclei of liquids formed in the vapor upon homogeneous nucleation support the idea of no significant dependence of σ on the curvature of the interface at the range of subnanometer radii.
Cite:
Fenelonov V.B.
, Kodenyov G.G.
, Kostrovsky V.G.
On the Dependence of Surface Tension of Liquids on the Curvature of the Liquid-Vapor Interface
The Journal of Physical Chemistry B. 2001. V.105. N5. P.1050-1055. DOI: 10.1021/jp9929972 WOS Scopus РИНЦ
On the Dependence of Surface Tension of Liquids on the Curvature of the Liquid-Vapor Interface
The Journal of Physical Chemistry B. 2001. V.105. N5. P.1050-1055. DOI: 10.1021/jp9929972 WOS Scopus РИНЦ
Dates:
Submitted: | Aug 24, 1999 |
Accepted: | Jun 1, 2000 |
Published online: | Jan 13, 2001 |
Published print: | Feb 1, 2001 |
Identifiers:
Web of science | WOS:000166846100019 |
Scopus | 2-s2.0-0035249849 |
Elibrary | 13387886 |
Chemical Abstracts | 2001:31831 |
Chemical Abstracts (print) | 134:106212 |
OpenAlex | W1986797752 |