One-Pot Natural Alcohol Amination Catalyzed by Gold-Containing Catalysts Conference attendances
Language | Английский | ||||||||||||
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Participant type | Устный | ||||||||||||
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EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources” 30 Aug - 4 Sep 2015 , Казань |
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Abstract:
The one-pot terpene alcohol amination, which is of high practical importance for the synthesis of complicated amines with specific physiological properties, was systematically studied in the presence of gold catalysts to obtain the knowledge about the key parameters determining the catalytic performance. The catalytic activity and product distribution were shown to be strongly dependent on the support properties, namely acidity and basicity, and conditions of the catalysts pretreatment. The Au/ZrO2 catalyst pretreated under oxidizing atmosphere was observed to be rather active resulting in total conversion of myrtenol and selectivity to corresponding amine of about 53%. The reaction kinetics was modeled based on mechanistic considerations with the catalyst deactivation step included in the mechanism.
Cite:
Demidova Y.S.
, Simakova I.L.
, Beloshapkin S.A.
, Warna J.
, Suslov E.V.
, Volcho K.P.
, Salakhutdinov N.F.
, Simakov A.V.
, Murzin D.Y.
One-Pot Natural Alcohol Amination Catalyzed by Gold-Containing Catalysts
EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources” 30 Aug - 4 Sep 2015
One-Pot Natural Alcohol Amination Catalyzed by Gold-Containing Catalysts
EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources” 30 Aug - 4 Sep 2015