On the Mechanism of Alcohol Insertion into the Carbonyl Group in the Coordination Sphere of Fe(III) tris-Hexafluoroacetylacetonate Научная публикация
Журнал |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Вых. Данные | Год: 1984, Том: 24, Номер: 3-4, Страницы: 347-350 Страниц : 4 DOI: 10.1007/BF02093454 | ||
Авторы |
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Организации |
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Реферат:
The kinetics of formation of hemiacetals in the Fe(III) coordination sphere resulting from the reaction of Fe(III)
tris-hexafluoroacetylacetonate with methanol has been studied by the stopped-flow method. Two molecules of methanol and coordinated hexafluoroacetylacetonate anion (HFA−) take part in the rate-determining step. The effect of the second molecule of alcohol can be attributed to catalysis of proton transfer from methanol to the HFA− ligand through the chain of hydrogen bonds in 6-membered cyclic structures.
Библиографическая ссылка:
Ivanchenko V.A.
, Nekipelov V.M.
, Zamaraev K.I.
On the Mechanism of Alcohol Insertion into the Carbonyl Group in the Coordination Sphere of Fe(III) tris-Hexafluoroacetylacetonate
Reaction Kinetics and Catalysis Letters. 1984. V.24. N3-4. P.347-350. DOI: 10.1007/BF02093454 WOS Scopus РИНЦ
On the Mechanism of Alcohol Insertion into the Carbonyl Group in the Coordination Sphere of Fe(III) tris-Hexafluoroacetylacetonate
Reaction Kinetics and Catalysis Letters. 1984. V.24. N3-4. P.347-350. DOI: 10.1007/BF02093454 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 18 июн. 1983 г. |
Принята к публикации: | 20 июл. 1983 г. |
Опубликована в печати: | 1 сент. 1984 г. |
Идентификаторы БД:
Web of science | WOS:A1984SK32500027 |
Scopus | 2-s2.0-0041115371 |
РИНЦ | 12671225 |
Chemical Abstracts | 1984:198399 |
Chemical Abstracts (print) | 100:198399 |
OpenAlex | W1976108521 |