Telomerization of Butadiene with Diethylamine Catalyzed by Ni, Pd and Pt Allyl Halide Complexes Научная публикация
Журнал |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Вых. Данные | Год: 1978, Том: 8, Номер: 2, Страницы: 263-268 Страниц : 6 DOI: 10.1007/BF02061315 | ||
Ключевые слова | Physical Chemistry; Catalysis; Halide; PPh3; Allyl | ||
Авторы |
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Организации |
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Реферат:
The telomerization of butadiene with diethylamine with the formation of the tertiary amine (C2H5)2NC8H13 is catalyzed by Ni, Pd and Pt allyl halide complexes. Triphenylphosphine increases the activity of such catalysts. The rate of telomerization depends strongly on the [PPh3]/[M] ratio (M=Pd and Pt) and increases in the series of metals: Ni<Pt<Pd. The activity of (π-C3H5PdCl)2 exceeds that of (π-C3H5)2 Pd by more than two orders of magnitude.
Библиографическая ссылка:
Lazutkin A.M.
, Lazutkina A.I.
Telomerization of Butadiene with Diethylamine Catalyzed by Ni, Pd and Pt Allyl Halide Complexes
Reaction Kinetics and Catalysis Letters. 1978. V.8. N2. P.263-268. DOI: 10.1007/BF02061315 WOS Scopus РИНЦ
Telomerization of Butadiene with Diethylamine Catalyzed by Ni, Pd and Pt Allyl Halide Complexes
Reaction Kinetics and Catalysis Letters. 1978. V.8. N2. P.263-268. DOI: 10.1007/BF02061315 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 15 июн. 1977 г. |
Принята к публикации: | 25 окт. 1977 г. |
Опубликована в печати: | 1 мар. 1978 г. |
Идентификаторы БД:
Web of science | WOS:A1978FE11300021 |
Scopus | 2-s2.0-34250277545 |
РИНЦ | 30905375 |
Chemical Abstracts | 1978:529006 |
Chemical Abstracts (print) | 89:129006 |
OpenAlex | W2022335793 |