Dependence of the Catalytic Properties of Cobalt Molybdate in Propylene Oxidation on the Surface Reduction and Oxygen Bond Energy Научная публикация
Журнал |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Вых. Данные | Год: 1977, Том: 7, Номер: 2, Страницы: 187-192 Страниц : 5 DOI: 10.1007/BF02061837 | ||
Ключевые слова | Oxygen; Steady State; Cobalt; Catalysis; Propylene | ||
Авторы |
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Организации |
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Реферат:
The dependences of the rate of partial propylene oxidation and of oxygen bond energy on the degree of cobalt molybdate reduction has been investigated by pulse and calorimetric methods. It has been found that upon reduction, the selectivity to acrolein and the oxygen bond energy increase. The steady state under the conditions examined is characterized by 22% surface reduction and the presence of uniform oxygen with a bond energy of about 85 kcal/mol.
Библиографическая ссылка:
Andrushkevich T.V.
, Boreskov G.K.
, Pankratiev Y.D.
, Popova G.Y.
, Kozmenko O.N.
, Kuliev A.R.
Dependence of the Catalytic Properties of Cobalt Molybdate in Propylene Oxidation on the Surface Reduction and Oxygen Bond Energy
Reaction Kinetics and Catalysis Letters. 1977. V.7. N2. P.187-192. DOI: 10.1007/BF02061837 WOS Scopus РИНЦ
Dependence of the Catalytic Properties of Cobalt Molybdate in Propylene Oxidation on the Surface Reduction and Oxygen Bond Energy
Reaction Kinetics and Catalysis Letters. 1977. V.7. N2. P.187-192. DOI: 10.1007/BF02061837 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 1 дек. 1976 г. |
Принята к публикации: | 25 янв. 1977 г. |
Опубликована в печати: | 1 июн. 1977 г. |
Идентификаторы БД:
Web of science | WOS:A1977DW14600012 |
Scopus | 2-s2.0-0039897969 |
РИНЦ | 31174447 |
Chemical Abstracts | 1977:583725 |
Chemical Abstracts (print) | 87:183725 |
OpenAlex | W1980557138 |