Reaction Paths of the Formation and Consumption of Nitroorganic Complex Intermediates in the Selective Catalytic Reduction of Nitrogen Oxides with Propylene on Zirconium Dioxide According to In Situ Fourier Transform IR Spectroscopic Data Научная публикация
Журнал |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Вых. Данные | Год: 2006, Том: 47, Номер: 4, Страницы: 593-602 Страниц : 10 DOI: 10.1134/S0023158406040161 | ||||||
Ключевые слова | Nitro Group; Selective Catalytic Reduction; Nitromethane; Nitrate Complex; Nitroethane | ||||||
Авторы |
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Организации |
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Реферат:
Nitrate, acetate, and nitroorganic complexes were detected on the surface of ZrO2 under the reaction conditions of nitrogen oxide reduction with propylene using Fourier transform IR spectroscopy. The nitroorganic complex was formed in the reaction between acetate and nitrate complexes by the replacement of the carboxyl group in the acetate complex by the nitro group. Monodentate nitrate was the most reactive species in this process. The adsorption of various nitroorganic substances was studied. It was found that the nitroorganic complex was structurally analogous to the nitromethane molecule bound to the surface through the nitro group. The experimental data led us to a conclusion that nitroorganic compounds were subsequently consumed in reactions with nitrate complexes. In this surface reaction, monodentate nitrate was also the most reactive species. The presence of oxygen had no effect on the consumption of the nitroorganic complex.
Библиографическая ссылка:
Matyshak V.A.
, Tretʹyakov V.F.
, Chernyshev K.A.
, Burdeinaya T.N.
, Korchak V.N.
, Sadykov V.A.
Reaction Paths of the Formation and Consumption of Nitroorganic Complex Intermediates in the Selective Catalytic Reduction of Nitrogen Oxides with Propylene on Zirconium Dioxide According to In Situ Fourier Transform IR Spectroscopic Data
Kinetics and Catalysis. 2006. V.47. N4. P.593-602. DOI: 10.1134/S0023158406040161 WOS Scopus РИНЦ
Reaction Paths of the Formation and Consumption of Nitroorganic Complex Intermediates in the Selective Catalytic Reduction of Nitrogen Oxides with Propylene on Zirconium Dioxide According to In Situ Fourier Transform IR Spectroscopic Data
Kinetics and Catalysis. 2006. V.47. N4. P.593-602. DOI: 10.1134/S0023158406040161 WOS Scopus РИНЦ
Оригинальная:
Матышак В.А.
, Третьяков В.Ф.
, Чернышов К.А.
, Бурдейная Т.Н.
, Корчак В.Н.
, Садыков В.А.
Маршруты образования и расходования нитроорганических комплексов -интермедиатов в селективном каталитическом восстановлении оксидов азота пропиленом на диоксиде циркония по данным ИК-Фурье-спектроскопии in situ
Кинетика и катализ. 2006. Т.47. №4. С.610-619. RSCI РИНЦ
Маршруты образования и расходования нитроорганических комплексов -интермедиатов в селективном каталитическом восстановлении оксидов азота пропиленом на диоксиде циркония по данным ИК-Фурье-спектроскопии in situ
Кинетика и катализ. 2006. Т.47. №4. С.610-619. RSCI РИНЦ
Даты:
Поступила в редакцию: | 25 янв. 2005 г. |
Опубликована в печати: | 1 июл. 2006 г. |
Идентификаторы БД:
Web of science | WOS:000239700700016 |
Scopus | 2-s2.0-33747099927 |
РИНЦ | 13515578 |
Chemical Abstracts | 2006:801529 |
Chemical Abstracts (print) | 146:142173 |
OpenAlex | W2082054924 |