Deposition of Au Thin Films and Nanoparticles by MOCVD Научная публикация
Журнал |
Chemical Vapor Deposition
ISSN: 0948-1907 , E-ISSN: 1521-3862 |
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Вых. Данные | Год: 2012, Том: 18, Номер: 10-12, Страницы: 336-342 Страниц : 7 DOI: 10.1002/cvde.201207004 | ||||
Ключевые слова | Gold nanoparticles, MOCVD, Morphology, Thin films, VUV activation | ||||
Авторы |
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Организации |
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Информация о финансировании (6)
1 | Министерство образования и науки Российской Федерации | 16.518.11.7019 |
2 | Российский фонд фундаментальных исследований | 12-03-01039 (01201258422) |
3 | Российский фонд фундаментальных исследований | 12-03-01154 |
4 | Российский фонд фундаментальных исследований | 10-03-01005 |
5 | Российский фонд фундаментальных исследований | 12-03-90840 |
6 | Президиум РАН | 24 |
Реферат:
Using metal-organic (MO)CVD, gold films and arrays of gold nanoparticles are obtained from volatile organometallic dimethylgold(III) complexes with O, N, S donor ligands. As precursors, such compounds as (CH3)2Au(OAc), (CH3)2Au(piv), (CH3)2Au(OQ), (CH3)2Au(SQ), (CH3)2Au(thd), and (CH3)2Au(dtc) were used. Deposition processes are carried out within a low pressure (LP)CVD reactor with additional vacuum ultraviolet (VUV) stimulation, with and without a hydrogen reactant gas. The influence of precursor structure on the morphology of the deposited layers is demonstrated. The use of precursor (CH3)2Au(OQ) results in obtaining ultra-thin continuous gold film ∼3 nm thick. It is established that with hydrogen reactant gas injected into the system, the amount of impurities in the film decreases. With the VUV stimulation, the gold content in the films amounts to almost 100%; in addition, the morphology of coatings is observed to change significantly. According to the X-ray diffraction (XRD) phase analysis, gold crystallites in the films grow mainly in the [111] direction.
Библиографическая ссылка:
Parkhomenko R.G.
, Morozova N.B.
, Zharkova G.I.
, Shubin Y.V.
, Trubin S.V.
, Kriventsov V.V.
, Kuchumov B.M.
, Koretskaya T.P.
, Igumenov I.K.
Deposition of Au Thin Films and Nanoparticles by MOCVD
Chemical Vapor Deposition. 2012. V.18. N10-12. P.336-342. DOI: 10.1002/cvde.201207004 WOS Scopus РИНЦ
Deposition of Au Thin Films and Nanoparticles by MOCVD
Chemical Vapor Deposition. 2012. V.18. N10-12. P.336-342. DOI: 10.1002/cvde.201207004 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 22 мая 2012 г. |
Принята к публикации: | 12 сент. 2012 г. |
Опубликована online: | 9 нояб. 2012 г. |
Опубликована в печати: | 1 дек. 2012 г. |
Идентификаторы БД:
Web of science | WOS:000312156200012 |
Scopus | 2-s2.0-84871313284 |
РИНЦ | 20488085 |
Chemical Abstracts | 2012:1805316 |
Chemical Abstracts (print) | 158:165500 |
OpenAlex | W2020345915 |