Compounds Featuring the Structural Fragment P-C-P Научная публикация
Журнал |
Phosphorus, Sulfur, and Silicon and the Related Elements (1989-current)
ISSN: 1563-5325 , E-ISSN: 1042-6507 |
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Вых. Данные | Год: 2011, Том: 186, Страницы: 621-625 Страниц : 5 DOI: 10.1080/10426507.2010.520285 | ||||||||||
Ключевые слова | Azaphospholes, Diphosphiranes, Hypervalency, Phosphanes, Ylides, Zwitterions | ||||||||||
Авторы |
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Организации |
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Информация о финансировании (4)
1 | German Research Foundation | |
2 | Alexander von Humboldt Foundation | |
3 | Swiss National Science Foundation | |
4 | Национальная академия наук Украины |
Реферат:
This article summarizes some of our investigations of compounds featuring the structural fragment P‒C‒P. Phosphorus atoms in different oxidation states and coordination numbers display different chemical behaviors. This may lead to unique chemical properties when they are bridged by a methylene group in a P‒CH2‒P system. For example, the PIII‒CH2‒PVunit is able to add different unsaturated compounds to give zwitterionic products with oppositely charged phosphorus atoms. In addition, the two hydrogen atoms in P‒CH2‒P may also take part in different transformations, resulting in the formation of carbodiphosphoranes or in the formation of a direct P-P bond to give three-membered ring diphosphiranes.
Библиографическая ссылка:
Shevchenko I.
, Tarasevych A.
, Turcheniuk K.
, Mikolenko R.
, Andrushko V.
, Rozhenko A.
, Schmutzler R.
, Grützmacher H.
, Röschenthaler G.-V.
Compounds Featuring the Structural Fragment P-C-P
Phosphorus, Sulfur, and Silicon and the Related Elements (1989-current). 2011. V.186. P.621-625. DOI: 10.1080/10426507.2010.520285 WOS Scopus РИНЦ
Compounds Featuring the Structural Fragment P-C-P
Phosphorus, Sulfur, and Silicon and the Related Elements (1989-current). 2011. V.186. P.621-625. DOI: 10.1080/10426507.2010.520285 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 5 июл. 2010 г. |
Принята к публикации: | 30 авг. 2010 г. |
Опубликована в печати: | 31 мар. 2011 г. |
Опубликована online: | 25 апр. 2011 г. |
Идентификаторы БД:
Web of science | WOS:000290046600002 |
Scopus | 2-s2.0-79955757364 |
РИНЦ | 27802668 |
Chemical Abstracts | 2011:520760 |
Chemical Abstracts (print) | 155:12024 |
OpenAlex | W2024291344 |