Kinetics, Modeling, and Process Design of Hydrogen Production by Aqueous Phase Reforming of Xylitol Научная публикация
Журнал |
Industrial and Engineering Chemistry Research
ISSN: 0888-5885 , E-ISSN: 1520-5045 |
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Вых. Данные | Год: 2017, Том: 56, Номер: 45, Страницы: 13240-13253 Страниц : 14 DOI: 10.1021/acs.iecr.7b01636 | ||||||||||
Ключевые слова | OXYGENATED HYDROCARBONS; CATALYSTS; ALKANES | ||||||||||
Авторы |
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Организации |
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Информация о финансировании (2)
1 | European Commission | 310490 FP7-NMP-2012-SMALL-6 SUSFUELCAT |
2 | Министерство образования и науки Российской Федерации | 14.Z50.31.0013 |
Реферат:
The present study was focused on kinetic investigation of xylitol aqueous phase reforming with 2.5%Pt/C catalyst in a fixed bed reactor. For kinetic modelling a complex reaction network was taken into account considering formation not only hydrogen and CO2, but also a range of alkanes in various side reactions. Parameter investigation revealed an
adequate description of the experimental data. Influence of mass transfer was elucidated by exploring the parameter space of diffusion and mass transfer coefficients as well as Peclet numbers. Aspen HYSYS software was used to design a hydrogen production plant with 500 kg/h capacity operating with xylitol as a feedstock. Heat consumption of the designed process can be fully covered by heat generated combusting alkanes formed during APR reaction.
Библиографическая ссылка:
Murzin D.Y.
, Garcia S.
, Russo V.
, Kilpiö T.
, Godina L.I.
, Tokarev A.V.
, Kirilin A.V.
, Simakova I.L.
, Poulston S.
, Sladkovskii D.A.
, Warna J.
Kinetics, Modeling, and Process Design of Hydrogen Production by Aqueous Phase Reforming of Xylitol
Industrial and Engineering Chemistry Research. 2017. V.56. N45. P.13240-13253. DOI: 10.1021/acs.iecr.7b01636 WOS Scopus РИНЦ
Kinetics, Modeling, and Process Design of Hydrogen Production by Aqueous Phase Reforming of Xylitol
Industrial and Engineering Chemistry Research. 2017. V.56. N45. P.13240-13253. DOI: 10.1021/acs.iecr.7b01636 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 18 апр. 2017 г. |
Принята к публикации: | 30 июн. 2017 г. |
Опубликована online: | 14 июл. 2017 г. |
Опубликована в печати: | 15 нояб. 2017 г. |
Идентификаторы БД:
Web of science | WOS:000415785500037 |
Scopus | 2-s2.0-85034043817 |
РИНЦ | 31053390 |
Chemical Abstracts | 2017:1100388 |
Chemical Abstracts (print) | 167:531729 |
OpenAlex | W2728062393 |