Effect of Preparation Conditions on Nanostructural Features of the NAFION® Type Perfluorinated Proton Conducting Membranes Научная публикация
Журнал |
Petroleum Chemistry
ISSN: 0965-5441 , E-ISSN: 1531-8532 |
||||||||
---|---|---|---|---|---|---|---|---|---|
Вых. Данные | Год: 2012, Том: 52, Номер: 8, Страницы: 565-570 Страниц : 6 DOI: 10.1134/S0965544112080105 | ||||||||
Ключевые слова | perfluorinated membranes, proton conductivity, small-angle neutron scattering, structure, water content | ||||||||
Авторы |
|
||||||||
Организации |
|
Информация о финансировании (1)
1 | Президиум РАН | 5.3.1. |
Реферат:
Features of the fine structure of three samples of perfluorinated Nafion® type membranes—Nafion-115, its Russian analogue MF-4SK, and a new similar material PFM-E produced according to our novel water-emulsion technique—have been characterized using the small-angle neutron scattering technique. A difference in the regularity of common elements of fine structure (cylindrical channels) in the membranes has been revealed. Nafion-115 has the most regular structure with a diffraction peak corresponding to the double channel diameter and an additional broad maximum in the scattering curve indicating a long-range order in the arrangement of straight cylindrical channels. For MF-4SK, in addition, twisted and less ordered channels have been observed. In the PFM-E sample channels have a tortuous and branched structure with diameters similar to Nafion-115. Only a short-range order (40–50 Å) in the arrangement of the channels has been detected, and correlation in their mutual orientation at longer distances is weakened. It has been supposed that the observed branched structure of the channels promotes an increase in water content and an improvement in proton conductivity.
Библиографическая ссылка:
Kulʹvelis Y.V.
, Lebedev V.T.
, Trunov V.A.
, Primachenko O.N.
, Khaikin S.Y.
, Torok D.
, Ivanchev S.S.
Effect of Preparation Conditions on Nanostructural Features of the NAFION® Type Perfluorinated Proton Conducting Membranes
Petroleum Chemistry. 2012. V.52. N8. P.565-570. DOI: 10.1134/S0965544112080105 WOS Scopus РИНЦ
Effect of Preparation Conditions on Nanostructural Features of the NAFION® Type Perfluorinated Proton Conducting Membranes
Petroleum Chemistry. 2012. V.52. N8. P.565-570. DOI: 10.1134/S0965544112080105 WOS Scopus РИНЦ
Оригинальная:
Кульвелис Ю.В.
, Лебедев В.Т.
, Трунов В.А.
, Примаченко О.Н.
, Хайкин С.Я.
, Торок Д.
, Иванчев С.С.
Влияние условий получения на наноструктурные особенности перфторированных протонопроводящих мембран типа NAFION®
Мембраны и мембранные технологии. 2012. Т.2. №3. С.179-185. РИНЦ
Влияние условий получения на наноструктурные особенности перфторированных протонопроводящих мембран типа NAFION®
Мембраны и мембранные технологии. 2012. Т.2. №3. С.179-185. РИНЦ
Даты:
Поступила в редакцию: | 8 мар. 2012 г. |
Опубликована в печати: | 1 дек. 2012 г. |
Опубликована online: | 7 янв. 2013 г. |
Идентификаторы БД:
Web of science | WOS:000313194500002 |
Scopus | 2-s2.0-84872379662 |
РИНЦ | 20485732 |
Chemical Abstracts | 2013:36275 |
Chemical Abstracts (print) | 158:303378 |
OpenAlex | W2327414978 |