One-Pot Natural Alcohol Amination Catalyzed by Gold-Containing Catalysts Тезисы доклада
Конференция |
EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources” 30 авг. - 4 сент. 2015 , Казань |
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Сборник | EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts Сборник, Boreskov Institute of Catalysis. Novosibirsk.2015. 2184 c. ISBN 9785906376107. РИНЦ |
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Вых. Данные | Год: 2015, Страницы: 1693-1694 Страниц : 2 | ||||||||||||
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Реферат:
The one-pot terpene alcohol amination, which is of high practical importance for the synthesis of complicated amines with specific physiological properties, was systematically studied in the presence of gold catalysts to obtain the knowledge about the key parameters determining the catalytic performance. The catalytic activity and product distribution were shown to be strongly dependent on the support properties, namely acidity and basicity, and conditions of the catalysts pretreatment. The Au/ZrO2 catalyst pretreated under oxidizing atmosphere was observed to be rather active resulting in total conversion of myrtenol and selectivity to corresponding amine of about 53%. The reaction kinetics was modeled based on mechanistic considerations with the catalyst deactivation step included in the mechanism.
Библиографическая ссылка:
Demidova Y.S.
, Simakova I.L.
, Beloshapkin S.
, Warna J.
, Suslov E.V.
, Volcho K.P.
, Salakhutdinov N.F.
, Simakov A.V.
, Murzin D.Y.
One-Pot Natural Alcohol Amination Catalyzed by Gold-Containing Catalysts
В сборнике EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts. – Boreskov Institute of Catalysis., 2015. – C.1693-1694. – ISBN 9785906376107.
One-Pot Natural Alcohol Amination Catalyzed by Gold-Containing Catalysts
В сборнике EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts. – Boreskov Institute of Catalysis., 2015. – C.1693-1694. – ISBN 9785906376107.
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