The Investigation of Chemical and Phase Composition of Solid Precursor of MoVTeNb Oxide Catalyst and Its Transformation During the Thermal Treatment Научная публикация
Журнал |
Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875 |
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Вых. Данные | Год: 2009, Том: 353, Номер: 2, Страницы: 249-257 Страниц : 8 DOI: 10.1016/j.apcata.2008.10.060 | ||||
Ключевые слова | Anderson-type anions, M1, M2, MoVTeNb oxide catalyst, Phase structure, Propane ammoxidation | ||||
Авторы |
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Организации |
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Реферат:
This work presents the investigation of chemical and phase composition of solid precursor of MoV0.3Te0.23Nb0.12Ox catalyst and its changes during the thermal treatment. The properties of the precursors and of the catalysts obtained by calcinations of precursors at 220–600 °C were characterized by BET, XRD, IR and Raman spectroscopy, HRTEM and differential dissolution methods. A MoVTeNb four-component heteropolycompound is formed upon mixing of the starting materials. Thermal decomposition of this precursor occurs in the temperature range from 220 to 350 °C, and it results in formation of highly dispersed uniformly distributed particles with a layered structure. These particles progressively transform into two amorphous phases of variable composition. The first phase is a three-component MoVxTeyOn and the second one is a four-component MoVgTepNbzOm phase. The change of the chemical and phase compositions completes at 550 °C; it yields well-crystallized phases with compositions corresponding to phases M2 (MoV0.35Te0.34) and M1 (MoV0.28Te0.1Nb0.12). Crystalline materials show the best catalytic performances in propane ammoxidation.
Библиографическая ссылка:
Popova G.Y.
, Andrushkevich T.V.
, Dovlitova L.S.
, Aleshina G.I.
, Chesalov Y.A.
, Ishenko A.V.
, Ishenko E.V.
, Plyasova L.M.
, Malakhov V.V.
, Khramov M.I.
The Investigation of Chemical and Phase Composition of Solid Precursor of MoVTeNb Oxide Catalyst and Its Transformation During the Thermal Treatment
Applied Catalysis A: General. 2009. V.353. N2. P.249-257. DOI: 10.1016/j.apcata.2008.10.060 WOS Scopus РИНЦ
The Investigation of Chemical and Phase Composition of Solid Precursor of MoVTeNb Oxide Catalyst and Its Transformation During the Thermal Treatment
Applied Catalysis A: General. 2009. V.353. N2. P.249-257. DOI: 10.1016/j.apcata.2008.10.060 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 18 июл. 2008 г. |
Принята к публикации: | 29 окт. 2008 г. |
Опубликована online: | 14 нояб. 2008 г. |
Опубликована в печати: | 1 февр. 2009 г. |
Идентификаторы БД:
Web of science | WOS:000263187800013 |
Scopus | 2-s2.0-58149187824 |
РИНЦ | 13614444 |
Chemical Abstracts | 2009:40118 |
Chemical Abstracts (print) | 150:306957 |
OpenAlex | W1970225275 |