Transition Metal Catalyzed Aerobic Asymmetric Coupling of 2-Naphthols Обзор
Журнал |
Mini-Reviews in Organic Chemistry
ISSN: 1570-193X , E-ISSN: 1875-6298 |
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Вых. Данные | Год: 2019, Том: 16, Номер: 4, Страницы: 392-398 Страниц : 7 DOI: 10.2174/1570193x15666180418153713 | ||||
Ключевые слова | Asymmetric synthesis, 2-naphthol, BINOL, aerobic oxidative coupling, transition metals, mechanism | ||||
Авторы |
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Организации |
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Информация о финансировании (2)
1 | Федеральное агентство научных организаций России | 0303-2016-0005 |
2 | Российский фонд фундаментальных исследований | 17-03-00991 |
Реферат:
Optically pure 1,1′-bi-2-naphthol (BINOL) and its derivatives are among the most widely used chiral ligands and auxiliaries for asymmetric synthesis. These molecules also occur as scaffolds for various biologically active compounds. Direct oxidative coupling of 2-naphthols in the presence of chiral catalysts provides a powerful strategy for the synthesis of optically pure 1,1′-bi-2-naphthols (BINOLS). In 1978, Wynberg with co-workers discovered that a copper salt with chiral auxiliary mediates the oxidative coupling of 2-naphthols, which can be taken as the starting point for further progress in this area. Over the last decades, a number of efficient and stereoselective catalyst systems have been developed. This mini-review surveys the aerobic asymmetric oxidative coupling of 2-naphthols catalyzed by transition metal complexes reported since 1995.
Библиографическая ссылка:
Tkachenko N.V.
, Bryliakov K.P.
Transition Metal Catalyzed Aerobic Asymmetric Coupling of 2-Naphthols
Mini-Reviews in Organic Chemistry. 2019. V.16. N4. P.392-398. DOI: 10.2174/1570193x15666180418153713 WOS Scopus РИНЦ
Transition Metal Catalyzed Aerobic Asymmetric Coupling of 2-Naphthols
Mini-Reviews in Organic Chemistry. 2019. V.16. N4. P.392-398. DOI: 10.2174/1570193x15666180418153713 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 23 февр. 2018 г. |
Принята к публикации: | 9 апр. 2018 г. |
Опубликована в печати: | 15 янв. 2019 г. |
Идентификаторы БД:
Web of science | WOS:000461717500009 |
Scopus | 2-s2.0-85063740892 |
РИНЦ | 38722800 |
Chemical Abstracts | 2019:667125 |
OpenAlex | W2801149897 |