Silicon and Germanium-Based Sesquioxanes as Versatile Building Blocks for Cage Metallacomplexes. A Review Обзор
Журнал |
Journal of Cluster Science
ISSN: 1040-7278 , E-ISSN: 1572-8862 |
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Вых. Данные | Год: 2019, Том: 30, Номер: 5, Страницы: 1283-1316 Страниц : 34 DOI: 10.1007/s10876-019-01567-y | ||||||||
Ключевые слова | Cage compounds; Catalytic activity; Coordination polymers; High-nuclearity; Metallagermsesquioxanes; Metallasilsesquioxanes; Single-crystal X-ray diffraction; Supramolecular design | ||||||||
Авторы |
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Организации |
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Информация о финансировании (4)
1 | Министерство образования и науки Российской Федерации | |
2 | Российский фонд фундаментальных исследований | 17-03-00993 |
3 | Министерство науки и высшего образования Российской Федерации | 0239-2019-0003 |
4 | Российский фонд фундаментальных исследований | 19-03-00488 (АААА-А19-119011690147-2) |
Реферат:
In the present paper, a rapidly developing field of polynuclear cage metallasilsesquioxanes and metallagermsesquioxanes chemistry is surveyed. Deliberate synthesis techniques aimed at the cages of specific nuclearity are described with the emphasis placed onto analysis of similarities and differences between silicon- and germanium-based substances. General approaches towards design of polymeric supramolecular assemblies based on cage metallasilsesquioxanes and metallagermsesquioxanes are outlined and illustrated with appropriate examples. Striking catalytic properties of the title compounds in homogeneous oxidation reactions are noted as one of their prospective application field.
Библиографическая ссылка:
Levitsky M.M.
, Zubavichus Y.V.
, Korlyukov A.A.
, Khrustalev V.N.
, Shubina E.S.
, Bilyachenko A.N.
Silicon and Germanium-Based Sesquioxanes as Versatile Building Blocks for Cage Metallacomplexes. A Review
Journal of Cluster Science. 2019. V.30. N5. P.1283-1316. DOI: 10.1007/s10876-019-01567-y WOS Scopus РИНЦ РИНЦ
Silicon and Germanium-Based Sesquioxanes as Versatile Building Blocks for Cage Metallacomplexes. A Review
Journal of Cluster Science. 2019. V.30. N5. P.1283-1316. DOI: 10.1007/s10876-019-01567-y WOS Scopus РИНЦ РИНЦ
Даты:
Поступила в редакцию: | 15 мар. 2019 г. |
Опубликована online: | 4 мая 2019 г. |
Опубликована в печати: | 1 сент. 2019 г. |
Идентификаторы БД:
Web of science | WOS:000487900100015 |
Scopus | 2-s2.0-85065395332 |
РИНЦ | 38690719 , 41792994 |
Chemical Abstracts | 2019:887763 |
OpenAlex | W2944365947 |