Metal-Organic Frameworks Based on Polynuclear Lanthanide Complexes and Octahedral Rhenium Clusters Научная публикация
Журнал |
Inorganic Chemistry Frontiers
ISSN: 2052-1545 , E-ISSN: 2052-1553 |
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Вых. Данные | Год: 2019, Том: 6, Номер: 6, Страницы: 1518-1526 Страниц : 9 DOI: 10.1039/c9qi00339h | ||||||||||
Ключевые слова | Binary alloys Crystalline materials Erbium alloys Organometallics Praseodymium alloys Rhenium Thermodynamic stability | ||||||||||
Авторы |
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Организации |
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Информация о финансировании (2)
1 | Министерство науки и высшего образования Российской Федерации | 0239-2019-0003 |
2 | Российский фонд фундаментальных исследований | 18-29-04007 (АААА-А18-118070990004-3) |
Реферат:
The octahedral chalcocyanide cluster anion [Re6S8(CN)6]4- can serve as a metallolinker for the self-assembly of metal-organic frameworks (MOFs) comprising polynuclear lanthanide complexes, which have been illustrated for a series of nine compounds isolated as [{Ln4(μ3-OH)4(ina)4(H2O)n}{Re6S8(CN)6}]·mH2O (Ln = Pr-Er, ina = isonicotinate). Their solid-state framework structures are based on {Ln4(μ3-OH)4}8+ cubane fragments interlinked by isonicotinate and rhenium cyanide clusters. The coordination environment of the lanthanide ions, the coordination numbers and even the number of bridging isonicotinate moieties changes systematically within the lanthanide row, however, the framework topology remains unchanged, confirming the structure-directing role of the rhenium cluster. Structures, magnetochemical properties, luminescence and thermal stability of the new MOFs have been thoroughly analyzed. © 2019 the Partner Organisations.
Библиографическая ссылка:
Litvinova Y.M.
, Gayfulin Y.M.
, van Leusen J.
, Samsonenko D.G.
, Lazarenko V.A.
, Zubavichus Y.V.
, Kögerler P.
, Mironov Y.V.
Metal-Organic Frameworks Based on Polynuclear Lanthanide Complexes and Octahedral Rhenium Clusters
Inorganic Chemistry Frontiers. 2019. V.6. N6. P.1518-1526. DOI: 10.1039/c9qi00339h WOS Scopus РИНЦ
Metal-Organic Frameworks Based on Polynuclear Lanthanide Complexes and Octahedral Rhenium Clusters
Inorganic Chemistry Frontiers. 2019. V.6. N6. P.1518-1526. DOI: 10.1039/c9qi00339h WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 27 мар. 2019 г. |
Принята к публикации: | 6 мая 2019 г. |
Опубликована online: | 6 мая 2019 г. |
Опубликована в печати: | 6 июн. 2019 г. |
Идентификаторы БД:
Web of science | WOS:000472193200021 |
Scopus | 2-s2.0-85067249651 |
РИНЦ | 41634880 |
Chemical Abstracts | 2019:884585 |
OpenAlex | W2944352503 |