Coordination Polymers of γ,γ'-Dipyridyl and Mononuclear Benzoates M(OOCPh)2[O(H)Me]4 (M = Ni, Co)
Научная публикация
| Общее |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Переводная
|
| Журнал |
Russian Journal of Inorganic Chemistry
ISSN: 0036-0236
, E-ISSN: 1531-8613
|
| Вых. Данные |
Год: 2019,
Том: 64,
Номер: 10,
Страницы: 1220-1228
Страниц
: 9
DOI:
10.1134/S0036023619100036
|
| Ключевые слова |
N-donor; nickel and cobalt benzoates; synthesis; X-ray diffraction analysis |
| Авторы |
Datchuk R.R.
1
,
Grineva A.A.
1
,
Uvarova M.A.
1
,
Yakushev I.A.
1
,
Zubavichus Ya.V.
2,3
,
Nefedov S.E.
1
|
| Организации |
| 1 |
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991 Russia
|
| 2 |
National Research Center “Kurchatov Institute”, Moscow, 123182 Russia
|
| 3 |
Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
|
|
Информация о финансировании (2)
|
1
|
Министерство науки и высшего образования Российской Федерации
|
|
|
2
|
Российский фонд фундаментальных исследований
|
18-33-01161 (АААА-А18-118112690025-8)
|
The slow diffusion of a γ,γ′-dipyridyl adduct solution in methanol into a methanol solution of the adduct M[(OOCPh]2[O(H)Me]4 (1) at the reagent ratio 1 : 1 and room temperature was found to result in the 1D coordination polymers {dipyM(OOCPh)2[O(H)Me]2}n (M = Ni (2), green; Co (3), orange) and {(dipy)2Co2(µ-OOCPh)2(η2-OOCPh)2 ⋅ MeOH}n (4), pink). Orange polymer 3 was the only product when the initial reagents were diluted three times, and their diffusion was performed at 5°C. Synthesized polymers 2–4 were studied by chemical and X-ray diffraction analyses and IR spectroscopy. © 2019, Pleiades Publishing, Ltd.