Some Transformations of trans-Tetrapyridine Complexes of Nitrosoruthenium: Crystal Structures of [Ru(NO)Py4(OH)](PF6)2 ⋅ (CH3)2CO and [H5O2]2[Ru(NO)Py4Cl]Cl4 Научная публикация
Журнал |
Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318 |
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Вых. Данные | Год: 2018, Том: 44, Номер: 10, Страницы: 613-618 Страниц : 6 DOI: 10.1134/s1070328418100093 | ||||
Ключевые слова | amino complexes; chloride complexes; hydroxo complexes; IR spectroscopy; nitrosoruthenium complexes; pyridine; X-ray structure analysis | ||||
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Реферат:
The slow evaporation of an acetone solution containing trans-[Ru(NO)Py4(OH)]2+ cations and hexafluorophosphate anions results in the crystallization of trans-[Ru(NO)Py4(OH)](PF6)2 ⋅ (CH3)2CO (I). The reactions of trans‑[Ru(NO)Py4(OH)]Cl2 ⋅ H2O with solutions of chloric or hydrochloric acid followed by the evaporation of the reaction solutions at ambient temperature afford trans-[Ru(NO)Py4(H2O)](ClO4)3 (II) or [H5O2]2[Ru(NO)Py4Cl]Cl4 (III), respectively. The obtained chloride complex III is unstable and at ambient temperature eliminates hydrogen chloride to transform into trans-[Ru(NO)Py4Cl]Cl2 ⋅ 4H2O (IV). The crystal structures of compounds I and III are determined by X-ray structure analysis (CIF files ССDC nos. 1421042 (I) and 1421041 (III)).
Библиографическая ссылка:
Makhinya A.N.
, Il'in M.A.
, Korolkov I.V.
, Baidina I.A.
Some Transformations of trans-Tetrapyridine Complexes of Nitrosoruthenium: Crystal Structures of [Ru(NO)Py4(OH)](PF6)2 ⋅ (CH3)2CO and [H5O2]2[Ru(NO)Py4Cl]Cl4
Russian Journal of Coordination Chemistry. 2018. V.44. N10. P.613-618. DOI: 10.1134/s1070328418100093 WOS Scopus РИНЦ
Some Transformations of trans-Tetrapyridine Complexes of Nitrosoruthenium: Crystal Structures of [Ru(NO)Py4(OH)](PF6)2 ⋅ (CH3)2CO and [H5O2]2[Ru(NO)Py4Cl]Cl4
Russian Journal of Coordination Chemistry. 2018. V.44. N10. P.613-618. DOI: 10.1134/s1070328418100093 WOS Scopus РИНЦ
Оригинальная:
Махиня А.Н.
, Ильин М.А.
, Корольков И.В.
, Байдина И.А.
Некоторые превращения транс-тетрапиридиновых комплексов нитрозорутения. Кристаллическое строение [Ru(NO)Py4(OH)](PF6)2 ⋅ (CH3)2CO И [H5O2]2[Ru(NO)Py4Cl]Cl4
Координационная химия. 2018. Т.44. №5. С.312-317. DOI: 10.1134/S0132344X18050092 РИНЦ
Некоторые превращения транс-тетрапиридиновых комплексов нитрозорутения. Кристаллическое строение [Ru(NO)Py4(OH)](PF6)2 ⋅ (CH3)2CO И [H5O2]2[Ru(NO)Py4Cl]Cl4
Координационная химия. 2018. Т.44. №5. С.312-317. DOI: 10.1134/S0132344X18050092 РИНЦ
Даты:
Поступила в редакцию: | 11 дек. 2017 г. |
Опубликована в печати: | 1 окт. 2018 г. |
Опубликована online: | 5 окт. 2018 г. |
Идентификаторы БД:
Web of science | WOS:000446542500005 |
Scopus | 2-s2.0-85054478295 |
РИНЦ | 38618691 |
Chemical Abstracts | 2018:1865101 |
OpenAlex | W2895522705 |