Transformations of Acetophenone and Its Derivatives in Supercritical Solvent Isopropanol/CO2 in a Continuous Flow Reactor in the Presence of Alumina Научная публикация
Журнал |
The Journal of Supercritical Fluids
ISSN: 0896-8446 , E-ISSN: 1872-8162 |
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Вых. Данные | Год: 2012, Том: 70, Страницы: 35-39 Страниц : 5 DOI: 10.1016/j.supflu.2012.05.012 | ||||||
Ключевые слова | Acetophenone, Alumina, Meerwein-Ponndorf-Verley reduction, Styrene, Supercritical CO 2, Supercritical isopropanol | ||||||
Авторы |
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Организации |
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Информация о финансировании (1)
1 | Российский фонд фундаментальных исследований | 11-08-00171 |
Реферат:
Acetophenone and its derivatives undergo various transformations in binary supercritical solvent isopropanol/CO2 in a flow reactor in the presence of granulated Al2O3. Depending on the reaction temperature, respective secondary alcohols, or isopropyl ethers, or substituted styrenes are formed at contact times of ~4 min. Selectivity for the reaction products attains 96% at high conversion of initial compounds. It was shown that the nature of a substitute in ketone aromatic ring exerts primary effect both on the conversion of initial compounds and on stability of intermediates under reaction conditions, and thus affects the end product distribution.
Библиографическая ссылка:
Sivcev V.P.
, Volcho K.P.
, Salakhutdinov N.F.
, Anikeev V.I.
Transformations of Acetophenone and Its Derivatives in Supercritical Solvent Isopropanol/CO2 in a Continuous Flow Reactor in the Presence of Alumina
The Journal of Supercritical Fluids. 2012. V.70. P.35-39. DOI: 10.1016/j.supflu.2012.05.012 WOS Scopus РИНЦ
Transformations of Acetophenone and Its Derivatives in Supercritical Solvent Isopropanol/CO2 in a Continuous Flow Reactor in the Presence of Alumina
The Journal of Supercritical Fluids. 2012. V.70. P.35-39. DOI: 10.1016/j.supflu.2012.05.012 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 13 апр. 2012 г. |
Принята к публикации: | 25 мая 2012 г. |
Опубликована online: | 15 июн. 2012 г. |
Опубликована в печати: | 1 окт. 2012 г. |
Идентификаторы БД:
Web of science | WOS:000309314800005 |
Scopus | 2-s2.0-84865700876 |
РИНЦ | 20473300 |
Chemical Abstracts | 2012:1303246 |
Chemical Abstracts (print) | 157:579775 |
OpenAlex | W2043333059 |