Liquid Phase Catalytic Hydrodechlorination of Chlorobenzene over Supported Nickel and Palladium Catalysts: An NMR Insight into Solvent Function Научная публикация
Журнал |
Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169 |
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Вых. Данные | Год: 2000, Том: 153, Номер: 1-2, Страницы: 231-236 Страниц : 6 DOI: 10.1016/S1381-1169(99)00352-0 | ||
Ключевые слова | 13C NMR, 2D NMR, Chlorobenzene, Hydrodechlorination, Nickel and palladium catalysts | ||
Авторы |
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Организации |
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Реферат:
The catalytic hydrodechlorination of chlorobenzene with Ni/C, Pd/C and Ni98Pd2/C in ethanol was studied with 2D and 13C{1H} NMR. Two dechlorination routes of this reaction (ionic and free-radical) are suggested depending upon the nature of the active hydrogen species. At the same time two competitive sources of hydrogen for hydrogenolysis of the CCl bond – molecular hydrogen and solvent (ethanol) molecules – are readily apparent from experiments with molecular deuterium.
Библиографическая ссылка:
Yakovlev V.A.
, Terskikh V.V.
, Simagina V.I.
, Likholobov V.A.
Liquid Phase Catalytic Hydrodechlorination of Chlorobenzene over Supported Nickel and Palladium Catalysts: An NMR Insight into Solvent Function
Journal of Molecular Catalysis A: Chemical. 2000. V.153. N1-2. P.231-236. DOI: 10.1016/S1381-1169(99)00352-0 WOS Scopus РИНЦ
Liquid Phase Catalytic Hydrodechlorination of Chlorobenzene over Supported Nickel and Palladium Catalysts: An NMR Insight into Solvent Function
Journal of Molecular Catalysis A: Chemical. 2000. V.153. N1-2. P.231-236. DOI: 10.1016/S1381-1169(99)00352-0 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 19 апр. 1999 г. |
Принята к публикации: | 13 сент. 1999 г. |
Опубликована в печати: | 10 мар. 2000 г. |
Опубликована online: | 13 мар. 2000 г. |
Идентификаторы БД:
Web of science | WOS:000085905200026 |
Scopus | 2-s2.0-0034628690 |
РИНЦ | 13353151 |
Chemical Abstracts | 2000:168952 |
Chemical Abstracts (print) | 132:323263 |
OpenAlex | W2035752172 |