Molybdophosphate Heteropoly Blues: Electron-Transfer Reactions in Aqueous Solutions as Studied by NMR Научная публикация
Журнал |
Polyhedron
ISSN: 0277-5387 |
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Вых. Данные | Год: 2013, Том: 65, Страницы: 54-59 Страниц : 6 DOI: 10.1016/j.poly.2013.08.014 | ||
Ключевые слова | Electron transfer, Molybdenum, NMR spectroscopy, Phosphorus, Polyoxometalates | ||
Авторы |
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Организации |
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Реферат:
Reduction of heteropolyacid H3[PMo12O40]·aq has been followed quantitatively by 31P NMR in its dilute aqueous solutions. The HPA anions (“blues”) reduced by one, two and four electrons were detected, and their relative concentrations were evaluated at different total degrees of reduction. The rate constants of the intermolecular electron transfer have been estimated for differently reduced species from their NMR line widths and intensities and compared with the calculated rate constants for the outer-sphere electron-transfer mechanism.
Библиографическая ссылка:
Maksimovskaya R.I.
Molybdophosphate Heteropoly Blues: Electron-Transfer Reactions in Aqueous Solutions as Studied by NMR
Polyhedron. 2013. V.65. P.54-59. DOI: 10.1016/j.poly.2013.08.014 WOS Scopus РИНЦ
Molybdophosphate Heteropoly Blues: Electron-Transfer Reactions in Aqueous Solutions as Studied by NMR
Polyhedron. 2013. V.65. P.54-59. DOI: 10.1016/j.poly.2013.08.014 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 24 мая 2013 г. |
Принята к публикации: | 4 авг. 2013 г. |
Опубликована online: | 14 авг. 2013 г. |
Опубликована в печати: | 28 нояб. 2013 г. |
Идентификаторы БД:
Web of science | WOS:000326999200007 |
Scopus | 2-s2.0-84883203418 |
РИНЦ | 20454363 |
Chemical Abstracts | 2013:1615302 |
Chemical Abstracts (print) | 159:674989 |
OpenAlex | W2058662424 |