Mechanochemical Synthesis of SiO44–-Substituted Hydroxyapatite, Part I – Kinetics of Interaction between the Components Научная публикация
Журнал |
European Journal of Inorganic Chemistry
ISSN: 1434-1948 , E-ISSN: 1099-0682 |
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Вых. Данные | Год: 2014, Том: 28, Страницы: 4803-4809 Страниц : 7 DOI: 10.1002/ejic.201402247 | ||||||
Ключевые слова | Doping, Hydroxyapatite, Kinetics, Mechanochemical synthesis, Silicon, Solid-phase synthesis | ||||||
Авторы |
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Организации |
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Информация о финансировании (2)
1 | Совет по грантам Президента Российской Федерации | НШ-2938.2014.3 |
2 | Министерство образования и науки Российской Федерации |
Реферат:
The kinetics of the room-temperature dry mechanochemical synthesis of hydroxyapatite modified by SiO44– ions has been studied for the first time. The changes in the composition of the reaction mixture as a function of the time of mechanical activation in a planetary ball mill as well as the composition of the final product have been investigated by X-ray phase analysis and IR spectroscopy. Certain stages of the interaction of the reactants have been analyzed with the help of high-resolution electron microscopy. The mechanochemical synthesis conducted in air is accompanied by the incorporation of carbonate ions into the apatite lattice, which results in the formation of B-type carbonated hydroxyapatite. The apatite structure starts to form after 5 min of mechanochemical activation of the reaction mixture, and the final single-phase nanocrystalline powder of silicate-substituted carbonated hydroxyapatite is formed after 30 min of activation.
Библиографическая ссылка:
Chaikina M.V.
, Bulina N.V.
, Ishchenko A.V.
, Prosanov I.Y.
Mechanochemical Synthesis of SiO44–-Substituted Hydroxyapatite, Part I – Kinetics of Interaction between the Components
European Journal of Inorganic Chemistry. 2014. V.28. P.4803-4809. DOI: 10.1002/ejic.201402247 WOS Scopus РИНЦ
Mechanochemical Synthesis of SiO44–-Substituted Hydroxyapatite, Part I – Kinetics of Interaction between the Components
European Journal of Inorganic Chemistry. 2014. V.28. P.4803-4809. DOI: 10.1002/ejic.201402247 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 31 мар. 2014 г. |
Опубликована online: | 6 авг. 2014 г. |
Опубликована в печати: | 1 окт. 2014 г. |
Идентификаторы БД:
Web of science | WOS:000342910600012 |
Scopus | 2-s2.0-84908880315 |
РИНЦ | 24001023 |
Chemical Abstracts | 2014:1279760 |
Chemical Abstracts (print) | 161:479575 |
OpenAlex | W1595796613 |