Cobalt Phthalocyanine Derivatives Supported on TiO2 by Sol-Gel Processing: Part 2. Activity in Sulfide and Ethanethiol Oxidation Научная публикация
Журнал |
Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169 |
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Вых. Данные | Год: 1999, Том: 140, Номер: 3, Страницы: 235-240 Страниц : 6 DOI: 10.1016/S1381-1169(98)00239-8 | ||||||
Ключевые слова | Catalytic activity, Cobalt phthalocyanines, Sulfide and ethanethiol oxidation, Supported catalysts, Titanium alkoxides | ||||||
Авторы |
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Организации |
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Информация о финансировании (1)
1 | International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union | 94/4612 |
Реферат:
The catalytic activity of cobalt(II) 2,9,16,23-tetrasulphophthalocyanine and cobalt(II) 2,9,16,23-tetra(chlorosulphonyl)phthalocyanine covalently bonded to a TiO2 matrix by sol–gel processing was investigated for sulfide and ethanethiol (CH3CH2SH) liquid-phase oxidation. A comparison of the kinetic data as well as the state of active component by using electron spectroscopy in dependence on precursors was carried out. Kinetic data shows that the most stable and active catalysts for ethanethiol oxidation are both CoPc(SO3H)4 and CoPc(SO2Cl)4 in TiO2 from Ti(OFull-size image (<1 K))4, whereas in the case of Na2S oxidation in neutral medium the activity of the former is higher.
Библиографическая ссылка:
Stuchinskaya T.
, Kundo N.
, Gogina L.
, Schubert U.
, Lorenz A.
, Maizlish V.
Cobalt Phthalocyanine Derivatives Supported on TiO2 by Sol-Gel Processing: Part 2. Activity in Sulfide and Ethanethiol Oxidation
Journal of Molecular Catalysis A: Chemical. 1999. V.140. N3. P.235-240. DOI: 10.1016/S1381-1169(98)00239-8 WOS Scopus РИНЦ
Cobalt Phthalocyanine Derivatives Supported on TiO2 by Sol-Gel Processing: Part 2. Activity in Sulfide and Ethanethiol Oxidation
Journal of Molecular Catalysis A: Chemical. 1999. V.140. N3. P.235-240. DOI: 10.1016/S1381-1169(98)00239-8 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 21 нояб. 1997 г. |
Принята к публикации: | 13 июл. 1998 г. |
Опубликована online: | 4 мар. 1999 г. |
Опубликована в печати: | 23 апр. 1999 г. |
Идентификаторы БД:
Web of science | WOS:000079179800003 |
Scopus | 2-s2.0-0033597428 |
РИНЦ | 13312441 |
Chemical Abstracts | 1999:210505 |
Chemical Abstracts (print) | 130:242790 |
OpenAlex | W2031406277 |