Study of Influence of cis-trans Isomerization on Selective Oxidations of Alkenes by Nitrous Oxide Доклады на конференциях
Язык | Английский | ||||
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Тип доклада | Стендовый | ||||
Конференция |
EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources” 30 авг. - 4 сент. 2015 , Казань |
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Реферат:
In the present work the influence of cis-trans isomerization of heptane-3 on reactivity of C=C bond of alkenes towards N2O as well as the contribution of the reaction route with the break of the initial double bounds were studied. It was shown that both cis- and trans-heptane isomers perform very similar reactivity. At the same time for trans-hepten-3 the contribution of the route with C-C bound break is approximately three times higher comparing with cis-heptane-3. The study reveals the common regularities of the oxidation of compounds with C=C bounds by nitrous oxide. The observed difference in contribution of the reaction route with C-C bound break for the olefins confirms the results obtained for rubbers previously.
Библиографическая ссылка:
Ivanov D.P.
, Semikolenov S.V.
, Nartova A.V.
, Fedorov V.S.
, Babushkin D.E.
, Dubkov K.A.
Study of Influence of cis-trans Isomerization on Selective Oxidations of Alkenes by Nitrous Oxide
EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources” 30 Aug - 4 Sep 2015
Study of Influence of cis-trans Isomerization on Selective Oxidations of Alkenes by Nitrous Oxide
EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources” 30 Aug - 4 Sep 2015