Process for preparing a catalyst component for polymerization of olefins
||Заявка на патент
||WO 2014118165 A1
|Номер заявки (21):
|Дата подачи заявки (22):
||28 янв. 2014 г.
|Дата начала отсчета срока действия патента (24):
|Дата публикации патента (44,45,46):
|Дата публикации заявки (43):
||7 авг. 2014 г.
The present invention relates to a process for preparing a catalyst component for polymerization of an olefin comprising the steps of: i) contacting a compound R9 zMgX2-z wherein R9 is aromatic, aliphatic or cyclo-aliphatic group containing up to 20 carbon atoms, X is a halide, and z is in a range of larger than 0 and smaller than 2, with an alkoxy- or aryloxy-containing silane compound to give a first intermediate reaction product; ii) contacting the first intermediate reaction product with at least one activating compound selected from the group formed by electron donors and compounds of formula M(OR10)V- w(OR11)w, wherein M can be Ti, Zr, Hf, Al or Si, and M(OR10)V-W(R11)W, wherein M is Si, each R10 and R11, independently, represent an alkyl, alkenyl or aryl group, v is the valency of M, v being either 3 or 4, and w is smaller than v, to give a second intermediate reaction product; and iii) contacting the second intermediate reaction product with a halogen-containing Ti-compound, a monoester as activating agent, a 1,3-diether as an internal electron donor, and optionally a diester as an additional internal electron donor.