Dimeric Structure and Electronic Conformation of Tb(CF3COO)3·3H2O According to Luminescence Data Full article
Journal |
Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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Output data | Year: 2001, Volume: 42, Number: 5, Pages: 759-766 Pages count : 8 DOI: 10.1023/A:1017965316032 | ||
Tags | Physical Chemistry; 3H2O; Inorganic Chemistry; Excited State; Diffraction Analysis | ||
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Abstract:
The results of X-ray diffraction and luminescence analyses of Tb(CF3COO)3⋅3H2O are presented. According to X-ray diffraction analysis, the compound is a centrosymmetric dimer. The electronic structure of this compound was established from the luminescence and excitation spectra. The energies of the singlet and triplet levels of the molecule were estimated and their positions in the structure of the terms of the terbium(III) ion as well as the nepheloxetic shift values were determined. It follows from the analysis of the luminescence spectra that the dimer molecule of the compound in the excited state is not centrosymmetric.
Cite:
Rastorguev A.A.
, Remova A.A.
, Romanenko G.V.
, Sokolova N.P.
, Belyi V.I.
, Larionov S.V.
Dimeric Structure and Electronic Conformation of Tb(CF3COO)3·3H2O According to Luminescence Data
Journal of Structural Chemistry. 2001. V.42. N5. P.759-766. DOI: 10.1023/A:1017965316032 WOS Scopus РИНЦ
Dimeric Structure and Electronic Conformation of Tb(CF3COO)3·3H2O According to Luminescence Data
Journal of Structural Chemistry. 2001. V.42. N5. P.759-766. DOI: 10.1023/A:1017965316032 WOS Scopus РИНЦ
ArticleLinkType.TRANSLATED_TO_ORIGINAL:
Расторгуев А.А.
, Ремова А.А.
, Романенко Г.В.
, Соколова Н.П.
, Белый В.И.
, Ларионов С.В.
Димерная структура Tb(CF3COO)3·3H2O и особенности его электронного строения по данным люминесцентного анализа
Журнал структурной химии. 2001. Т.42. №5. С.907-916.
Димерная структура Tb(CF3COO)3·3H2O и особенности его электронного строения по данным люминесцентного анализа
Журнал структурной химии. 2001. Т.42. №5. С.907-916.
Dates:
Submitted: | Mar 5, 2001 |
Published print: | Sep 1, 2001 |
Identifiers:
Web of science | WOS:000174566300009 |
Scopus | 2-s2.0-0035562025 |
Elibrary | 5031050 |
Chemical Abstracts | 2002:240096 |
Chemical Abstracts (print) | 137:83886 |
OpenAlex | W2912040943 |