Mechanism of Carboxylic Acid Formation on Vanadium-Containing Oxide Catalysts Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 2005, Volume: 46, Number: 2, Pages: 217-226 Pages count : 10 DOI: 10.1007/s10975-005-0069-9 | ||
Tags | Formaldehyde; Nicotinates; Vanadium; Acid Formation; Carboxylic Acid | ||
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Abstract:
The surface intermediates in acrolein oxidation into acrylic acid on a V-Mo oxide catalyst, formaldehyde oxidation into formic acid on a V-Ti catalyst, and 3-pyridinecarboxaldehyde and β-picoline oxidation into nicotinic acid on a V-Ti catalyst are identified by in situ IR spectroscopy. The acids are found to form by similar mechanisms. The intermediates in acid formation are saltlike surface compounds (formates, acrylates, and nicotinates) stabilized on vanadium ions. The role of vanadium in acid formation is discussed in terms of the mechanisms suggested.
Cite:
Popova G.Y.
, Andrushkevich T.V.
, Zakharov I.I.
, Chesalov Y.A.
Mechanism of Carboxylic Acid Formation on Vanadium-Containing Oxide Catalysts
Kinetics and Catalysis. 2005. V.46. N2. P.217-226. DOI: 10.1007/s10975-005-0069-9 WOS Scopus РИНЦ
Mechanism of Carboxylic Acid Formation on Vanadium-Containing Oxide Catalysts
Kinetics and Catalysis. 2005. V.46. N2. P.217-226. DOI: 10.1007/s10975-005-0069-9 WOS Scopus РИНЦ
Original:
Попова Г.Я.
, Андрушкевич Т.В.
, Захаров И.И.
, Чесалов Ю.А.
Механизм образования карбоновых кислот на оксидных ванадийсодержащих катализаторах
Кинетика и катализ. 2005. Т.46. №2. С.233-242. RSCI РИНЦ
Механизм образования карбоновых кислот на оксидных ванадийсодержащих катализаторах
Кинетика и катализ. 2005. Т.46. №2. С.233-242. RSCI РИНЦ
Dates:
Submitted: | Jan 15, 2003 |
Published print: | Mar 1, 2005 |
Identifiers:
Web of science | WOS:000228933000005 |
Scopus | 2-s2.0-18244373439 |
Elibrary | 13493493 |
Chemical Abstracts | 2005:380941 |
Chemical Abstracts (print) | 144:90013 |
OpenAlex | W2090019166 |