TiO2 Photocatalytic Oxidation: II. Gas-Phase Processes Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 2005, Volume: 46, Number: 3, Pages: 422–436 Pages count : 15 DOI: 10.1007/s10975-005-0095-7 | ||||
Tags | TiO2; Sulfide; Reaction Center; Organic Substance; Photocatalytic Degradation | ||||
Authors |
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Affiliations |
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Funding (5)
1 | Civilian Research and Development Foundation | NO-008-X1 |
2 | Russian Foundation for Basic Research | 02-03-08002 |
3 | Suomen Akatemia | 208134 |
4 | Council for Grants of the President of the Russian Federation | НШ-1484.2003.3 |
5 | Russian Science Support Foundation |
Abstract:
The results of studies on the TiO2 photocatalytic oxidation of model air pollutants are summarized. The kinetics of photocatalytic oxidation of CO and the vapors of a number of simple organic substances was studied in detail. It was found that, in the course of reaction, all of the test substances underwent complete mineralization. Gaseous substrates were converted with the participation of several types of reaction centers. The photocatalytic oxidation of sulfur- and phosphorus-containing substances resulted in gradual deactivation of the photocatalyst; however, its activity can be restored by washing the photocatalyst with water. It was found that, along with oxidation, the steps of hydrolysis play an important role in the photocatalytic degradation of air pollutants, such as dimethyl methylphosphonate and 2-chloroethyl sulfide.
Cite:
Vorontsov A.V.
, Kozlov D.V.
, Smirniotis P.G.
, Parmon V.N.
TiO2 Photocatalytic Oxidation: II. Gas-Phase Processes
Kinetics and Catalysis. 2005. V.46. N3. P.422–436. DOI: 10.1007/s10975-005-0095-7 WOS Scopus РИНЦ РИНЦ
TiO2 Photocatalytic Oxidation: II. Gas-Phase Processes
Kinetics and Catalysis. 2005. V.46. N3. P.422–436. DOI: 10.1007/s10975-005-0095-7 WOS Scopus РИНЦ РИНЦ
ArticleLinkType.TRANSLATED_TO_ORIGINAL:
Воронцов А.В.
, Козлов Д.В.
, Смирниотис П.Г.
, Пармон В.Н.
Фотокаталитическое окисление на ТiO2 II. Процессы в газовой фазе
Кинетика и катализ. 2005. Т.46. №3. С.450-465. RSCI РИНЦ
Фотокаталитическое окисление на ТiO2 II. Процессы в газовой фазе
Кинетика и катализ. 2005. Т.46. №3. С.450-465. RSCI РИНЦ
Dates:
Submitted: | Apr 30, 2004 |
Published print: | May 1, 2005 |
Identifiers:
Web of science | WOS:000230024100020 |
Scopus | 2-s2.0-21544465063 |
Elibrary | 29494908 , 31122811 |
Chemical Abstracts | 2005:557863 |
Chemical Abstracts (print) | 143:391443 |
OpenAlex | W1984430510 |