Formation of Liquid Phase in the Carbon-Metal System at Unusually Low Temperature Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 1998, Volume: 39, Number: 4, Pages: 561-570 Pages count : 10 | ||
Tags | AMORPHOUS-CARBON; COBALT CATALYSTS; NICKEL; GRAPHITIZATION; PARTICLES; IRON; Pd; Ni | ||
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Abstract:
A phenomenon of the formation of liquid mobile metal-carbon particles is experimentally studied at comparatively low temperatures (600-700 °С) in a vacuum during the reaction of Fe, Co, and Ni with amorphous carbon and catalytic graphitization of carbon. A mechanism of the formation and maintenance of a liquid state of these particles is proposed and characterized by transient and pseudo-steady-state regimes. The liquid particles (catalytic intermediates) are abnormally supersaturated solutions of carbon in metal (up to 50 at. % at 700 °С).
Cite:
Krivoruchko O.P.
, Zaikovskii V.I.
Formation of Liquid Phase in the Carbon-Metal System at Unusually Low Temperature
Kinetics and Catalysis. 1998. V.39. N4. P.561-570. WOS Scopus РИНЦ
Formation of Liquid Phase in the Carbon-Metal System at Unusually Low Temperature
Kinetics and Catalysis. 1998. V.39. N4. P.561-570. WOS Scopus РИНЦ
Original:
Криворучко О.П.
, Зайковский В.И.
Образование жидкой фазы в системе углерод-металл при необычно низкой температуре
Кинетика и катализ. 1998. Т.39. №4. С.607-617. РИНЦ
Образование жидкой фазы в системе углерод-металл при необычно низкой температуре
Кинетика и катализ. 1998. Т.39. №4. С.607-617. РИНЦ
Dates:
Submitted: | Jul 25, 1997 |
Published print: | Jul 1, 1998 |
Identifiers:
Web of science | WOS:000076157100020 |
Scopus | 2-s2.0-0001419915 |
Elibrary | 13304186 |
Chemical Abstracts | 1998:653477 |
Chemical Abstracts (print) | 129:236167 |