Polyoxometalates for the Study of Active Sites in Catalytic Transformations of Organic Substances Review
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 1999, Volume: 40, Number: 5, Pages: 622-637 Pages count : 16 | ||
Tags | TERT-BUTYL ETHER; METAL SUBSTITUTED HETEROPOLYTUNGSTATES; HYDROGEN-PEROXIDE; CRYSTAL-STRUCTURE; CRYSTALLIZATION BEHAVIOR; IONIC-CONDUCTIVITY; BENZENE OXIDATION; ACIDIC PROPERTIES; OXO-TRANSFER; GAS-PHASE | ||
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Abstract:
The article reviews original studies of the catalytic properties of heteropoly compounds with various compositions and structures in the liquid-phase acidic, and oxidative reactions of organic substances. The methods for heteropoly compound synthesis using of electrodialysis, mechanochemistry, and reverse-osmotic membrane separation of ions are considered New methods for the synthesis of soluble mono- and polynuclear complexes from transition metal ions (M) and PW11MO39n--based heteropoly compounds, and the preparation of metal coil olds stabilized by isopoly and heteropoly compounds are proposed. The activity in acidic reactions is determined by the Bronsted acidity along with the structure of the heteropoly compound anion. The interaction between M and a heteropoly compound and the type of an additional ligand in the coordination sphere of M play a critical role in hydrocarbon oxidation by oxygen donors (H2O2, t-BuOOH, and O-2/H-2 mixtures).
Cite:
Kuznetsova L.I.
, Maksimov G.M.
, Likholobov V.A.
Polyoxometalates for the Study of Active Sites in Catalytic Transformations of Organic Substances
Kinetics and Catalysis. 1999. V.40. N5. P.622-637. WOS Scopus РИНЦ
Polyoxometalates for the Study of Active Sites in Catalytic Transformations of Organic Substances
Kinetics and Catalysis. 1999. V.40. N5. P.622-637. WOS Scopus РИНЦ
ArticleLinkType.TRANSLATED_TO_ORIGINAL:
Кузнецова Л.И.
, Максимов Г.М.
, Лихолобов В.А.
Использование полиоксометаллатов для изучения природы активных центров катализаторов превращения органических веществ
Кинетика и катализ. 1999. Т.40. №5. С.688-704. РИНЦ
Использование полиоксометаллатов для изучения природы активных центров катализаторов превращения органических веществ
Кинетика и катализ. 1999. Т.40. №5. С.688-704. РИНЦ
Dates:
Submitted: | Apr 26, 1999 |
Identifiers:
Web of science | WOS:000083503200004 |
Scopus | 2-s2.0-0033201265 |
Elibrary | 13310282 |
Chemical Abstracts | 1999:721540 |
Chemical Abstracts (print) | 132:55345 |