Molecular Aspects of Catalysis by Sulfides Review
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 1999, Volume: 40, Number: 6, Pages: 811-818 Pages count : 8 | ||
Tags | X-RAY ABSORPTION; HYDRODESULFURIZATION CATALYSTS; THIOPHENE HYDROGENOLYSIS; ELECTRONIC-STRUCTURE; OXIDATIVE ADDITION; SUPPORT; SILICA; ENVIRONMENT; DIHYDROGEN; COMPLEXES | ||
Authors |
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Affiliations |
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Abstract:
The paper presents a review of the comprehensive studies on the molecular structure of the active component of sulfide catalysts for the hydrorefining of oil fractions and the molecular mechanism of their action. An alternative approach to catalysis by sulfides is developed based on the experimental findings and the quantum-chemical studies. The notion on the oxidative addition and occlusion of hydrogen in the active component of sulfide hydrodesulfurization catalysts was examined and justified. The concerted mechanism of thiophene hydrogenolysis over sulfide bimetallic catalysts of different chemical compositions received further support.
Cite:
Startsev A.N.
Molecular Aspects of Catalysis by Sulfides
Kinetics and Catalysis. 1999. V.40. N6. P.811-818. WOS Scopus РИНЦ
Molecular Aspects of Catalysis by Sulfides
Kinetics and Catalysis. 1999. V.40. N6. P.811-818. WOS Scopus РИНЦ
Original:
Старцев А.Н.
Молекулярные аспекты катализа сульфидами
Кинетика и катализ. 1999. Т.40. №6. С.898-905. РИНЦ
Молекулярные аспекты катализа сульфидами
Кинетика и катализ. 1999. Т.40. №6. С.898-905. РИНЦ
Dates:
Submitted: | Apr 19, 1999 |
Identifiers:
Web of science | WOS:000084606000008 |
Scopus | 2-s2.0-0001269180 |
Elibrary | 13321987 |
Chemical Abstracts | 2000:34070 |
Chemical Abstracts (print) | 132:95362 |