Structure and Composition of the Anionic Chloride Complexes of Copper(II) as the Precursors of Catalysts for C-C1 Bond Metathesis Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 2002, Volume: 43, Number: 3, Pages: 408-411 Pages count : 4 DOI: 10.1023/A:1016018204168 | ||||||
Tags | Copper; Spectroscopy; Chloride; Physical Chemistry; Catalysis | ||||||
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Abstract:
The chloride complexes of copper(II) (catalysts or catalyst precursors for various reactions of halogenated hydrocarbons) were characterized using electron, EPR, and EXAFS spectroscopy. It was found that chlorocuprates occur as mononuclear ([CuCl4]2–), binuclear ([Cu2Cl6]2–), and, probably, polynuclear species in chlorobenzene solutions. The Cu–Cl bond length in [CuCl4]2– is 2.25 ± 0.2 Å, which is close to the same values for crystalline tetrachlorocuprates. It was assumed that the chloride complexes of copper with counterions occur as globules in chlorobenzene.
Cite:
Golubeva E.N.
, Kokorin A.I.
, Kochubey D.I.
, Pergushov V.I.
, Kriventsov V.V.
Structure and Composition of the Anionic Chloride Complexes of Copper(II) as the Precursors of Catalysts for C-C1 Bond Metathesis
Kinetics and Catalysis. 2002. V.43. N3. P.408-411. DOI: 10.1023/A:1016018204168 WOS Scopus РИНЦ
Structure and Composition of the Anionic Chloride Complexes of Copper(II) as the Precursors of Catalysts for C-C1 Bond Metathesis
Kinetics and Catalysis. 2002. V.43. N3. P.408-411. DOI: 10.1023/A:1016018204168 WOS Scopus РИНЦ
Original:
Голубева Е.Н.
, Кокорин А.И.
, Кочубей Д.И.
, Пергушов В.И.
, Кривенцов В.В.
Состав и строение анионных хлоридных комплексов меди(II) - предшественников катализаторов метатезиса связи C-Cl
Кинетика и катализ. 2002. Т.43. №3. С.440-444. РИНЦ
Состав и строение анионных хлоридных комплексов меди(II) - предшественников катализаторов метатезиса связи C-Cl
Кинетика и катализ. 2002. Т.43. №3. С.440-444. РИНЦ
Dates:
Submitted: | Apr 5, 2001 |
Published print: | May 1, 2002 |
Identifiers:
Web of science | WOS:000176749200013 |
Scopus | 2-s2.0-0038755317 |
Elibrary | 13409041 |
Chemical Abstracts | 2002:484298 |
Chemical Abstracts (print) | 137:206962 |
OpenAlex | W1508257777 |