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Stationary Kinetics of Light Olefin Oxidation by Hydrogen Peroxide in Aqueous Alkali Solutions in the Presence of Fe(III) Oxide Full article

Общее Language: Английский, Genre: Full article,
Status: Published, Source type: Translated
Journal Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Output data Year: 2002, Volume: 43, Number: 6, Pages: 778-784 Pages count : 7 DOI: 10.1023/A:1021630502721
Authors Lysova A.A. 1,2 , Kuzmin A.O. 2 , Elizarova G.L. 2 , Parmon V.N. 1,2
Affiliations
1 Novosibirsk State University, Novosibirsk, 630090 Russia
2 Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk, 630090 Russia

Funding (1)

1 Russian Foundation for Basic Research 00-15-97446

Abstract: The steady-state kinetics of ethylene and propylene oxidation by hydrogen peroxide in the presence of Fe(III) oxide in aqueous solutions with the permanent adding of H2O2 to the reaction medium was studied. The use of an original method for the study of the steady-state reaction kinetics with gas chromatographic detection of substrate consumption from the gas phase made it possible to estimate the apparent rate constants of ethylene oxidation, the ratio of the rate constants of propylene and ethylene oxidation, the reaction orders with respect to the substrate and oxidant concentration, the dependence of the apparent rate constant of ethylene oxidation on the catalyst weight and on the pH of solution, and the apparent activation energy of the process under condition of substrate distribution between the gas and liquid phases. It was found that the kinetic isotope effect in ethylene oxidation is almost absent when completely deuterated ethylene is used.
Cite: Lysova A.A. , Kuzmin A.O. , Elizarova G.L. , Parmon V.N.
Stationary Kinetics of Light Olefin Oxidation by Hydrogen Peroxide in Aqueous Alkali Solutions in the Presence of Fe(III) Oxide
Kinetics and Catalysis. 2002. V.43. N6. P.778-784. DOI: 10.1023/A:1021630502721 publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type
ArticleLinkType.TRANSLATED_TO_ORIGINAL: Лысова А.А. , Кузьмин А.О. , Елизарова Г.Л. , Пармон В.Н.
Стационарная кинетика окисления легких олефинов пероксидом водорода в щелочных водных растворах в присутствии оксида Fe(III)
Кинетика и катализ. 2002. Т.43. №6. С.835-842. publication_identifier_short.rinz_identifier_type
Dates:
Submitted: Dec 13, 2001
Published print: Nov 1, 2002
Identifiers:
publication_identifier.wos_identifier_type WOS:000180278200005
publication_identifier.scopus_identifier_type 2-s2.0-0037900750
publication_identifier.rinz_identifier_type 13402516
publication_identifier.accession_number_identifier_type 2002:967220
publication_identifier.chemical_accession_number_identifier_type 138:303817
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