Characterization of the Nickel-Amesite-Chlorite-Vermiculite System. Part I. Silicon Binding in Ni-Mg-Al Phylloaluminosilicates Full article
Journal |
PCCP: Physical Chemistry Chemical Physics
ISSN: 1463-9076 , E-ISSN: 1463-9084 |
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Output data | Year: 2003, Volume: 5, Number: 18, Pages: 4025-4031 Pages count : 7 DOI: 10.1039/b304272c | ||
Tags | attapulgite; chlorine derivative; hydrogen; methane; nickel complex; silicon; silicon derivative; vermiculite | ||
Authors |
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Affiliations |
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Funding (3)
1 | North Atlantic Treaty Organization | SfP-972557 |
2 | Siberian Branch of the Russian Academy of Sciences | |
3 | International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union | YSF 2002-282 |
Abstract:
Synthetic TO (1 tetrahedral layer/1 octahedral layer) phylloaluminosilicates of Ni–Mg–Al with amesite (septechlorite) structure were synthesized and their evolution during calcination in inert and reducing media was studied. After treatment at 700–800 °C in hydrogen, the samples consisted of dispersed metallic nickel particles supported on TOT Mg-chlorite-vermiculite; none of the catalysts studied contained SiO2. The samples were stable in inert gas and hydrogen atmospheres at 850 °C, as well as in hydrogen plus steam at 20 bar and 650 °C. Thus, we consider Ni-containing amesite-like compounds to be suitable catalysts for the methane steam reforming process.
Cite:
Khassin A.A.
, Yurieva T.M.
, Demeshkina M.P.
, Kustova G.N.
, Itenberg I.S.
, Kaichev V.V.
, Plyasova L.M.
, Anufrienko V.F.
, Molina I.Y.
, Larina T.V.
, Baronskaya N.A.
, Parmon V.N.
Characterization of the Nickel-Amesite-Chlorite-Vermiculite System. Part I. Silicon Binding in Ni-Mg-Al Phylloaluminosilicates
PCCP: Physical Chemistry Chemical Physics. 2003. V.5. N18. P.4025-4031. DOI: 10.1039/b304272c WOS Scopus РИНЦ
Characterization of the Nickel-Amesite-Chlorite-Vermiculite System. Part I. Silicon Binding in Ni-Mg-Al Phylloaluminosilicates
PCCP: Physical Chemistry Chemical Physics. 2003. V.5. N18. P.4025-4031. DOI: 10.1039/b304272c WOS Scopus РИНЦ
Dates:
Submitted: | Apr 17, 2003 |
Accepted: | Aug 7, 2003 |
Published online: | Aug 21, 2003 |
Published print: | Sep 1, 2003 |
Identifiers:
Web of science | WOS:000185740700031 |
Scopus | 2-s2.0-0141792170 |
Elibrary | 13421341 |
Chemical Abstracts | 2003:702341 |
Chemical Abstracts (print) | 140:29233 |
OpenAlex | W2107364879 |