Hydroisomerization of n-Hexadecane on Bifunctional Catalysts Based on Zeolites with Different Structures Full article
Journal |
Petroleum Chemistry
ISSN: 0965-5441 , E-ISSN: 1531-8532 |
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Output data | Year: 2002, Volume: 42, Number: 3, Pages: 192-198 Pages count : 7 | ||||
Tags | aluminosilicate calcium; aluminum phosphate; hexadecane; hydrogen; methylisoparaffin; paraffin; silicaaluminophosphate; unclassified drug; zeolite | ||||
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Abstract:
The influence of the ratio between the hydrogenating-dehydrogenating and acidic functions of bifunctional catalysts prepared from crystalline aluminosilicates and silicaaluminophosphates of different structural types on the selectivity of n-hexadecane transformation in a hydrogen atmosphere was studied. The ratio of the hydroisomerization to hydrocracking products was shown to be determined by the ratio of the acidic to hydro-dehydrogenating activities of the catalyst and the structural characteristics of the initial zeolite or silicaaluminophosphate. The dependence of the amount of isoparaffins on the crystallographic size of channels of the base zeolite is nonmonotonic in character, with a maximum at 0.62-0.63 nm, which corresponds to the kinetic diameter of monomethylisoparaffins.
Cite:
Lopatkin S.V.
, Ione K.G.
Hydroisomerization of n-Hexadecane on Bifunctional Catalysts Based on Zeolites with Different Structures
Petroleum Chemistry. 2002. V.42. N3. P.192-198. WOS Scopus РИНЦ
Hydroisomerization of n-Hexadecane on Bifunctional Catalysts Based on Zeolites with Different Structures
Petroleum Chemistry. 2002. V.42. N3. P.192-198. WOS Scopus РИНЦ
ArticleLinkType.TRANSLATED_TO_ORIGINAL:
Лопаткин С.В.
, Ионе К.Г.
Гидроизомеризация н-гексадекана на бифункциональных катализаторах с цеолитами различной структуры
Нефтехимия. 2002. Т.42. №3. С.214-221. Scopus РИНЦ
Гидроизомеризация н-гексадекана на бифункциональных катализаторах с цеолитами различной структуры
Нефтехимия. 2002. Т.42. №3. С.214-221. Scopus РИНЦ
Dates:
Submitted: | Dec 17, 2001 |
Published print: | May 1, 2002 |
Identifiers:
Web of science | WOS:000176289300006 |
Scopus | 2-s2.0-0036590035 |
Elibrary | 13413100 |