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Partial Oxidation of Methane to Synthesis Gas on Pt Electrode in a Solid Oxide Electrolyte Cell Full article

Общее Language: Английский, Genre: Full article,
Status: Published, Source type: Original
Journal Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837
Output data Year: 1996, Volume: 58, Number: 2, Pages: 407-416 Pages count : 10 DOI: 10.1007/BF02067052
Tags Methane, Partial oxidation, Platinum electrode-catalyst, Solid oxide electrolyte cell, Synthesis gas
Authors Galvita V.V. 1 , Belyaev V.D. 1 , Sobyanin V.A. 1
Affiliations
1 Federal Scientific Center, Boreskov Institute of Catalysis, Novosibirsk, 630090, Russia

Funding (2)

1 International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union 94-3056
2 Russian Foundation for Basic Research 93-03-05097

Abstract: The partial oxidation of methane to synthesis gas or oxyreforming of methane over a Pt electrode in a solid oxide electrolyte cell CH4+O2,Pt | ZrO2 (10mol%Y2O3)|Pt,air has been studied under open and closed circuit conditions. Experiments were performed at atmospheric pressure over a temperature range of 700–800°C and methane/oxygen ratios of 0.4–1.8. The Pt electrode was found to be an active electrode-catalyst for oxyreforming of methane and electrochemical oxidation of the oxyreforming products. The mechanism of methane oxyreforming and the effect of anodic current passing through the cell on the catalytic properties of the Pt electrode for oxyreforming of methane are discussed.
Cite: Galvita V.V. , Belyaev V.D. , Sobyanin V.A.
Partial Oxidation of Methane to Synthesis Gas on Pt Electrode in a Solid Oxide Electrolyte Cell
Reaction Kinetics and Catalysis Letters. 1996. V.58. N2. P.407-416. DOI: 10.1007/BF02067052 publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type
Dates:
Submitted: Dec 25, 1995
Accepted: Feb 5, 1996
Published print: Jul 1, 1996
Identifiers:
publication_identifier.wos_identifier_type WOS:A1996VT97600028
publication_identifier.scopus_identifier_type 2-s2.0-0342879063
publication_identifier.rinz_identifier_type 13247737
publication_identifier.accession_number_identifier_type 1996:744854
publication_identifier.chemical_accession_number_identifier_type 126:149663
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